One of the most remarkable results of the progress of molecular science is the light it has thrown on the nature of irreversible processes—processes, that is, which always tend towards and never away from a certain limiting state. Thus, if two gases be put into the same vessel, they become mixed, and the mixture tends continually to become more uniform. If two unequally heated portions of the same gas are put into the vessel, something of the kind takes place, and the whole tends to become of the same temperature. If two unequally heated solid bodies be placed in contact, a continual approximation of both to an intermediate temperature takes place.
In the case of the two gases, a separation may be effected by chemical means; but in the other two cases the former state of things cannot be restored by any natural process.
In the case of the conduction or diffusion of heat the process is not only irreversible, but it involves the irreversible diminution of that part of the whole stock of thermal energy which is capable of being converted into mechanical work.
This is Thomson’s theory of the irreversible dissipation of energy, and it is equivalent to the doctrine of Clausius concerning the growth of what he calls Entropy.
The irreversible character of this process is strikingly embodied in Fourier’s theory of the conduction of heat, where the formulae themselves indicate, for all positive values of the time, a possible solution which continually tends to the form of a uniform diffusion of heat.
But if we attempt to ascend the stream of time by giving to its symbol continually diminishing values, we are led up to a state of things in which the formula has what is called a critical value; and if we inquire into the state of things the instant before, we find that the formula becomes absurd.
We thus arrive at the conception of a state of things which cannot be conceived as the physical result of a previous state of things, and we find that this critical condition actually existed at an epoch not in the utmost depths of a past eternity, but separated from the present time by a finite interval.
This idea of a beginning is one which the physical researches of recent times have brought home to us, more than any observer of the course of scientific thought in former times would have had reason to expect.
But the mind of man is not, like Fourier’s heated body, continually settling down into an ultimate state of quiet uniformity, the character of which we can already predict; it is rather like a tree, shooting out branches which adapt themselves to the new aspects of the sky towards which they climb, and roots which contort themselves among the strange strata of the earth into which they delve. To us who breathe only the spirit of our own age, and know only the characteristics of contemporary thought, it is as impossible to predict the general tone of the science of the future as it is to anticipate the particular discoveries which it will make.