Five of Maxwell's Papers eBook

This eBook from the Gutenberg Project consists of approximately 50 pages of information about Five of Maxwell's Papers.

Five of Maxwell's Papers eBook

This eBook from the Gutenberg Project consists of approximately 50 pages of information about Five of Maxwell's Papers.

The rate of electrolytic conduction is, according to Wiedemann’s theory, influenced by the same cause; and the conduction of heat in fluids depends probably on the same kind of action.  In the case of gases, a molecular theory has been developed by Clausius and others, capable of mathematical treatment, and subjected to experimental investigation; and by this theory nearly every known mechanical property of gases has been explained on dynamical principles; so that the properties of individual gaseous molecules are in a fair way to become objects of scientific research.

Now Mr Stoney has pointed out[1] that the numerical results of experiments on gases render it probable that the mean distance of their particles at the ordinary temperature and pressure is a quantity of the same order of magnitude as a millionth of a millimetre, and Sir William Thomson has since[2] shewn, by several independent lines of argument, drawn from phenomena so different in themselves as the electrification of metals by contact, the tension of soap-bubbles, and the friction of air, that in ordinary solids and liquids the average distance between contiguous molecules is less than the hundred-millionth, and greater than the two-thousand-millionth of a centimetre.

[1] Phil.  Mag., Aug. 1868. [2] Nature, March 31, 1870.

These, of course, are exceedingly rough estimates, for they are derived from measurements some of which are still confessedly very rough; but if at the present time, we can form even a rough plan for arriving at results of this kind, we may hope that, as our means of experimental inquiry become more accurate and more varied, our conception of a molecule will become more definite, so that we may be able at no distant period to estimate its weight with a greater degree of precision.

A theory, which Sir W. Thomson has founded on Helmholtz’s splendid hydrodynamical theorems, seeks for the properties of molecules in the ring vortices of a uniform, frictionless, incompressible fluid.  Such whirling rings may be seen when an experienced smoker sends out a dexterous puff of smoke into the still air, but a more evanescent phenomenon it is difficult to conceive.  This evanescence is owing to the viscosity of the air; but Helmholtz has shewn that in a perfect fluid such a whirling ring, if once generated, would go on whirling for ever, would always consist of the very same portion of the fluid which was first set whirling, and could never be cut in two by any natural cause.  The generation of a ring-vortex is of course equally beyond the power of natural causes, but once generated, it has the properties of individuality, permanence in quantity, and indestructibility.  It is also the recipient of impulse and of energy, which is all we can affirm of matter; and these ring-vortices are capable of such varied connexions and knotted self-involutions, that the properties of differently knotted vortices must be as different as those of different kinds of molecules can be.

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Five of Maxwell's Papers from Project Gutenberg. Public domain.