The most important electro-chemical work of the future is to devise some means of obtaining nitrogen from the air. It is stated by scientists that the nitrogen of the soil is being exhausted and that at some future time the Earth may not be able to bear crops sufficient for the sustenance of man, unless some artificial means be found to replenish the nitrogen. Unlimited supplies of nitrogen exist in the air, but to fix it with other materials in such form that it will be useful as a fertilizer has been one of the problems to which the electro-chemists have recently devoted much attention. By the use of the electric arc and passing air through a furnace, various substances have been tried to take up the nitrogen of the air. Thus when calcium carbide is heated and brought into contact with nitrogen one atom of carbon is given up and two atoms of nitrogen take its place, resulting in the production of cyanamide.
Other important electro-chemical processes are involved in the electrolysis of the various alkaline salts to obtain metallic sodium and such products as chlorates. Thus by the electrolysis of sodium chloride metallic sodium and chlorine is obtained. From the metallic sodium solid caustic soda is then derived by a secondary reaction, while the chlorine is combined with lime to form chloride of lime or bleaching powder. In some processes the electrolysis affords directly an alkaline hypochlorite or a chlorate, the former being of wide commercial use as a bleaching agent in textile works and in the paper industry. The same process employed in the electrolysis of sodium salts is used in the case of magnesium and calcium.
Electrolysis is also made use of in the manufacture of chloroform and iodoform, as the chlorine or iodine which is produced in the electrolytic cell is allowed to act upon the alcohol or acetone under such conditions that chloroform or iodoform is produced.
Electro-chemistry plays an important part in many other industries whose omission from our description must not be considered as indicating any lack of their importance. New processes constantly are being discovered which may range all the way from the production of artificial gems to the wholesale production of the most common chemicals used in the arts. In many branches of chemical industry manufacturing processes have been completely changed, and from the research laboratories, which all large progressive manufacturers now maintain, as well as from workers in universities and scientific schools, new methods and discoveries are constantly forthcoming.
CHAPTER XII.
Electric railways.