at all. The positive electricity of the zinc appears
to traverse the liquid to the copper, from which it
flows through the wire to the zinc. The effect
is that the end of the wire attached to the copper
is positive (+), and called the positive “pole”
or electrode, while the end attached to the zinc is
negative (-), and called the negative pole or electrode.
“A simple and easy way to avoid confusion as
to the direction of the current, is to remember that
the
positive current flows
from the
copper
to the
zinc at the point of
metallic
contact.” The generation of this current
is accompanied by chemical action in the cell.
Experiment shows that the mere
contact of dissimilar
materials, such as copper and zinc, electrifies them—zinc
being positive and copper negative; but contact alone
does not yield a continuous current of electricity.
When we plunge the two metals, still in contact, either
directly or through a wire, into water preferably
acidulated, a chemical action is set up, the water
is decomposed, and the zinc is consumed. Water,
as is well known, consists of oxygen and hydrogen.
The oxygen combines with the zinc to form oxide of
zinc, and the hydrogen is set free as gas at the surface
of the copper plate. So long as this process
goes on, that is to say, as long as there is zinc
and water left, we get an electric current in the
circuit. The existence of such a current may be
proved by a very simple experiment. Place a penny
above and a dime below the tip of the tongue, then
bring their edges into contact, and you will feel
an acid taste in the mouth.
Figure 12 illustrates the supposed chemical action
in the cell. On the left hand are the zinc and
copper plates (Z C) disconnected in the liquid.
The atoms of zinc are shown by small circles; the
molecules of water, that is, oxygen, and hydrogen (H2O)
by lozenges of unequal size. On the right hand
the plates are connected by a wire outside the cell;
the current starts, and the chemical action begins.
An atom of zinc unites with an atom of oxygen, leaving
two atoms of hydrogen thus set free to combine with
another atom of oxygen, which in turn frees two atoms
of hydrogen. This interchange of atoms goes on
until the two atoms of hydrogen which are freed last
abide on the surface of the copper. The “contact
electricity” of the zinc and copper probably
begins the process, and the chemical action keeps
it up. Oxygen, being an “electro-negative”
element in chemistry, is attracted to the zinc, and
hydrogen, being “electro-positive,” is
attracted to the copper.
The difference of electrical condition or “potential”
between the plates by which the current is started
has been called the electromotive force, or force
which puts the electricity in motion. The obstruction
or hindrance which the electricity overcomes in passing
through its conductor is known as the resistance.
Obviously the higher the electromotive force and the
lower the resistance, the stronger will be the current
in the conductor. Hence it is desirable to have
a cell which will give a high electromotive force
and a low internal resistance.