handled without producing any other effect than a
feeling of intense cold. The particles of the
carbonic acid being so closely approximated in the
solid, the whole force of cohesive attraction (which
in the fluid is weak) becomes exerted, and opposes
its tendency to assume its gaseous state; but as it
receives heat from surrounding bodies, it passes into
gas gradually and without violence. The transition
of solid carbonic acid into gas deprives all around
it of caloric so rapidly and to so great an extent,
that a degree of cold is produced immeasurably great,
the greatest indeed known. Ten, twenty, or more
pounds weight of mercury, brought into contact with
a mixture of ether and solid carbonic acid, becomes
in a few moments firm and malleable. This, however,
cannot be accomplished without considerable danger.
A melancholy accident occurred at Paris, which will
probably prevent for the future the formation of solid
carbonic acid in these large quantities, and deprive
the next generation of the gratification of witnessing
these curious experiments. Just before the commencement
of the lecture in the Laboratory of the Polytechnic
School, an iron cylinder, two feet and a half long
and one foot in diameter, in which carbonic acid had
been developed for experiment before the class, burst,
and its fragments were scattered about with the most
tremendous force; it cut off both the legs of the
assistant and killed him on the spot. This vessel,
formed of the strongest cast-iron, and shaped like
a cannon, had often been employed to exhibit experiments
in the presence of the students. We can scarcely
think, without shuddering, of the dreadful calamity
such an explosion would have occasioned in a hall filled
with spectators.
When we had ascertained the fact of gases becoming
fluid under the influence of cold or pressure, a curious
property possessed by charcoal, that of absorbing
gas to the extent of many times its volume,—ten,
twenty, or even as in the case of ammoniacal gas or
muriatic acid gas, eighty or ninety fold,—which
had been long known, no longer remained a mystery.
Some gases are absorbed and condensed within the pores
of the charcoal, into a space several hundred times
smaller than they before occupied; and there is now
no doubt they there become fluid, or assume a solid
state. As in a thousand other instances, chemical
action here supplants mechanical forces. Adhesion
or heterogeneous attraction, as it is termed, acquired
by this discovery a more extended meaning; it had never
before been thought of as a cause of change of state
in matter; but it is now evident that a gas adheres
to the surface of a solid body by the same force which
condenses it into a liquid.