“The solution of double cyanide of gold, silver, and potassium, which has been drained from the leaching vats, is passed over the mercury in the precipitating ‘box’ when the decomposition of the electrolyte by the electric current is being accomplished, the gold and silver are set free and unite with the mercury, and are also deposited on the plates or discs of copper, forming amalgam, which is collected and made marketable by the well known and tried methods. The above solution is regenerated with cyanide of potassium by the setting free of the metals in the passage over the ‘box.’
“In using this solution again for a fresh charge of pulp, it is reinforced to the desired percentage, or strengthened with cyanide of potassium and other chemicals, and is always in good condition for continuing the operation of dissolving.
“The potassium acting on the water of the solution creates nascent hydrogen and potassium hydrate; the nascent hydrogen sets free the metals (gold and silver), which are precipitated into the mercury and form amalgam, leaving hydrocyanic acid; this latter combines with the potassium hydrate of the former reaction, thus forming cyanide of potassium. There are other reactions for which I have not at present the chemical formulas.
“As the solution passes over the mercury, the centre compartment of the ‘box’ is moved slowly longitudinally, which spreads the mercury, the solution is agitated and comes in perfect contact with the mercury, as well as the amalgamated plates or discs of copper, ensuring a perfect precipitation.
“It is not always necessary to precipitate all the gold and silver from the solution, for it is used over and over again indefinitely; but when it is required, it can be done perfectly and cheaply in a very short time.
“No solution leached from the pulp, containing cyanide of potassium, gold and silver, need be run to waste, which is in itself an enormous saving over the use of zinc shavings when handling large quantities of pulp and solution.
“Some of the advantages the electro-chemical process has over other cyanide processes are: Its cleanliness, quickness of action, cheapness, and large saving of cyanide of potassium by regeneration; not wasting the solutions, larger recovery of the gold and silver from the solutions; the cost of recovery less; the loss of gold, silver, and cyanide of potassium reduced to a minimum; the use of caustic alkali in such quantity as may be desired to keep the cyanide solution from being destroyed by the solidity of the pulp, and also sometimes to give warmth, as a warm cyanide solution will dissolve gold and silver quicker than a cold one. These caustic alkalies do not interfere with or prevent the perfect precipitation of the metals. The bullion recovered in this process is very fine, while the zinc-precipitated bullion is only about 700 fine.
“The gold and silver is dissolved, and then precipitated in one operation, which we know cannot be done in the ’chlorination process’; besides, the cost of plant and treatment is much less in the above-described process.