Wilkinson found that when the solution of gold chloride was as strong as, say, four grains to the ounce of water, that the pyrites or other base began to decompose, and the iron sulphide changed to yellow oxide, the “gossan” of our lodes, and that though the gold was deposited, this occurred in an irregular way, and it was coated with a dark brown powdery film something like the “black gold,” often found in drifts containing much ferruginous matter. Such were the curious Victorian nuggets Spondulix and Lothair.
Professor Newbery also made a number of similar experiments, and arrived at like results. He states as follows: “I placed a cube of galena in a solution of chloride of gold, with free access of air, and put in organic matter; gold was deposited as usual, in a bright metallic film, apparently completely coating the cube. After a few months the film burst along the edges of the cube, and remained in that state with the cracks open without any further alteration in size or form being apparent. Upon removing it a few days ago and breaking it open, I found that a large portion of the galena had been decomposed, forming chloride and sulphate of lead and free sulphur, which were mixed together, encasing a small nucleus of undecomposed sulphate of lead. The formation of these salts had exerted sufficient force to burst open the gold coating, which upon the outside had the mammillary form noticed by Wilkinson, while the inside was rough and irregular with crystals forcing their way into the lead salts. Had this action continued undisturbed, the result would have been a nugget with a nucleus of lead salts, or if there had been a current to remove the results of decomposition, a nugget without a nucleus of foreign matter.”