by Pliny, owed their destruction not to a change in
the colours, not to the alteration of the calcareous
ground on which they were painted, but to the decay
of the tablets of wood on which the intonaco or stucco
was laid. Amongst the substances employed in
building, wood, iron, tin, and lead, are most liable
to decay from the operation of water, then marble,
when exposed to its influence in the fluid form; brass,
copper, granite, sienite, and porphyry are more durable.
But in stones, much depends upon the peculiar nature
of their constituent parts; when the feldspar of the
granite rocks contains little alkali or calcareous
earth, it is a very permanent stone; but, when in granite,
porphyry, or sienite, either the feldspar contains
much alkaline matter, or the mica, schorl, or hornblende
much protoxide of iron, the action of water containing
oxygen and carbonic acid on the ferruginous elements
tends to produce the disintegration of the stone.
The red granite, black sienite, and red porphyry
of Egypt, which are seen at Rome in obelisks, columns,
and sarcophagi, are amongst the most durable compound
stones; but the grey granites of Corsica and Elba
are extremely liable to undergo alteration: the
feldspar contains much alkaline matter; and the mica
and schorl, much protoxide of iron. A remarkable
instance of the decay of granite may be seen in the
Hanging Tower of Pisa; whilst the marble pillars in
the basement remain scarcely altered, the granite ones
have lost a considerable portion of their surface,
which falls off continually in scales, and exhibits
everywhere stains from the formation of peroxide of
iron. The kaolin, or clay, used in most countries
for the manufacture of fine porcelain or china, is
generally produced from the feldspar of decomposing
granite, in which the cause of decay is the dissolution
and separation of the alkaline ingredients.
Eub.—I have seen serpentines, basalts,
and lavas which internally were dark, and which from
their weight, I should suppose, must contain oxide
of iron, superficially brown or red, and decomposing.
Undoubtedly this was from the action of water impregnated
with air upon their ferruginous elements.
The Unknown.—You are perfectly right.
There are few compound stones, possessing a considerable
specific gravity, which are not liable to change from
this cause; and oxide of iron amongst the metallic
substances anciently known, is the most generally
diffused in nature, and most concerned in the changes
which take place on the surface of the globe.
The chemical action of carbonic acid is so much connected
with that of water, that it is scarcely possible to
speak of them separately, as must be evident from
what I have before said; but the same action which
is exerted by the acid dissolved in water is likewise
exerted by it in its elastic state, and in this case
the facility with which the quantity is changed makes
up for the difference of the degree of condensation.