Scientific American Supplement, No. 717, September 28, 1889 eBook

This eBook from the Gutenberg Project consists of approximately 147 pages of information about Scientific American Supplement, No. 717, September 28, 1889.

Scientific American Supplement, No. 717, September 28, 1889 eBook

This eBook from the Gutenberg Project consists of approximately 147 pages of information about Scientific American Supplement, No. 717, September 28, 1889.

The distinguishing feature of this battery is that the electrolyte is not employed as a mobile liquid, but in a quasi-solid form, and it is, therefore, named dry gas battery.  It consists of a number of elements, which are formed of a porous diaphragm of a non-conducting material (in this instance plaster of Paris), which is impregnated with dilute sulphuric acid.  Both sides of this diaphragm are covered with very fine platinum leaf perforated with very numerous small holes, and over this a thin film of platinum black.  Both these coatings are in contact with frameworks of lead and antimony, insulated one from the other, which conduct the electricity to the poles of the battery.

A number of these elements are placed side by side, with non-conducting frames intervening, so as to form chambers through which the hydrogen gas is passed along one side of the element and air along the other.

This peculiar construction allows us to get a very large amount of duty from a very small amount of platinum.  One of the batteries before you, consisting of seven elements, with a total effective surface of half a square meter, contains 21/2 grammes of platinum leaf and 7 grammes of platinum black, a total of 91/2 grammes of platinum, and produces a current of 2 amperes and 5 volts, or 10 watts, when the outer resistance is properly adjusted.  This current is equal to nearly 50 per cent. of the total energy obtainable from the hydrogen absorbed in the battery.

In order to maintain a constant current, we have from time to time (say once an hour) to interchange the gases, so as to counteract the disturbing influence produced by the transport of the sulphuric acid gas from one side of the diaphragm to the other.  This operation can easily be performed automatically by a commutator worked by a clock.

The water produced in the battery by the oxidation of the hydrogen is carried off by the inert gas mixed with the hydrogen, and by the air, of which we use a certain excess for this purpose.  This is important, as if the platinum black becomes wet, it loses its absorbing power for the gases almost completely and stops the work of the battery.  To avoid this was in fact the great difficulty in designing a powerful gas battery, and all previous constructions which employed the electrolyte as a mobile liquid failed in consequence.

The results obtained by our battery are practically the same whether pure oxygen and hydrogen or air and gases containing 25 per cent. of hydrogen are used; but we found that the latter gases must be practically free from carbonic oxide and hydrocarbons, which both interfere very much with the absorbing power of the platinum black.

We had thus to find a cheap method of eliminating these two gases from the producer gas, and converting them at the same time into their equivalent of hydrogen.  The processes hitherto known for this purpose, viz., passing a mixture of such gases with steam over lime (which I mentioned some time ago) or over oxide of iron or manganese, require high temperatures, which render them expensive, and the latter do not effect the reaction to a sufficient extent for our purpose.

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Scientific American Supplement, No. 717, September 28, 1889 from Project Gutenberg. Public domain.