We have tried many experiments to produce hydrochloric acid in the producers, with the hope of thereby increasing the yield of ammonia, as it is well known that ammonium chloride vapor, although it consists of a mixture of ammonia gas and hydrochloric acid gas, is not at all dissociated at temperatures at which the dissociation of ammonia alone has already taken place to a considerable extent.
I had also hoped that I might in this way produce the acid necessary to combine with the ammonia at very small cost. For this purpose we moistened the fuel used with concentrated brine, and also with the waste liquors from the ammonia soda manufacture, consisting mainly of chloride of calcium; and we also introduced with the fuel balls made by mixing very concentrated chloride of calcium solution with clay, which allowed us to produce a larger quantity of hydrochloric acid in the producer than by the other methods.
We did in this way succeed in producing hydrochloric acid sometimes less and sometimes more than was necessary to combine with the ammonia, but we did not succeed in producing with regularity the exact amount of acid necessary to neutralize the ammonia. When the ammonia was in excess, we had therefore to use sulphuric acid as before to absorb this excess, and we were never certain that sometimes the hydrochloric acid might not be in excess, which would have necessitated to construct the whole plant so that it could have resisted the action of weak hydrochloric acid—a difficulty which I have not ventured to attack. The yield of ammonia was not in any case increased by the presence of the hydrochloric acid. This explains itself if we consider that there is only a very small amount of ammonia and hydrochloric acid