Scientific American Supplement, No. 717, September 28, 1889 eBook

This eBook from the Gutenberg Project consists of approximately 147 pages of information about Scientific American Supplement, No. 717, September 28, 1889.

Scientific American Supplement, No. 717, September 28, 1889 eBook

This eBook from the Gutenberg Project consists of approximately 147 pages of information about Scientific American Supplement, No. 717, September 28, 1889.

The gas we obtain contains, in a dry state, on an average, 15 per cent. of carbonic acid, 10 per cent. of carbonic oxide, 23 per cent. of hydrogen, 3 per cent. of hydrocarbons, and 49 per cent. of nitrogen.

The caloric value of this gas is very nearly equal to 73 per cent. of the caloric value of the fuel used, but in using this gas for heating purposes, such as raising steam or making salt, we utilize the heat it can give very much better than in burning fuel, as we can completely burn it with almost the theoretical quantity of air, so that the products of combustion resulting do not contain more than 1 to 2 per cent. of free oxygen.  Consequently the heat escaping into the chimney is very much less than when fuel is burnt direct, and we arrive at evaporating, by means of the gas, 85 per cent. of the water that we would evaporate by burning the fuel direct, in ordinary fireplaces.

We have, however, to use a certain quantity of steam in the producers and in evaporating the sulphate of ammonia liquors, which has to be deducted from the steam that can be raised by the gas in order to get at the quantity of available steam therefrom obtainable.  The former amounts, as already stated, to 0.6 ton, the latter to 0.1 ton of steam per ton of fuel burnt, making a total of 0.7 ton.  The gas obtained from one ton of fuel evaporates 5.8 tons of water in good steam boilers, working at a rate of evaporation of 50 to 55 tons per 24 hours under 90 lb. pressure.  Deducting from this the 0.7 ton necessary for working the plant leaves an available amount of steam raised by the gas from one ton of fuel of 5.1 tons, equal to 75 per cent. of the steam that we can obtain from the same fuel by hand firing.

In addition to the gas, we obtain about 3 per cent. of tar from the fuel.  This tar is very thick, and of little commercial value.  It contains only 4 per cent. of oils volatile below 200 deg.  C., and 38 per cent. of oils of a higher boiling point, consisting mostly of creosote oils very similar to those obtained from blast furnaces; and only small quantities of anthracene and paraffin wax.

I have made no attempts to utilize this tar except as fuel.  It evaporates nearly twice as much water as its weight of coal, and we have thus to add its evaporative efficiency to that of the gas given above, leading to a total of about 80 per cent. of the evaporative efficiency of the fuel used in the producers.  The loss involved in gasifying the fuel to recover the ammonia therefrom amounts thus to 20 per cent. of the fuel used.  This means that, where we have now to burn 100 tons of fuel, we shall have to burn 125 tons in the producers in order to obtain ammonia equal to about half the nitrogen contained therein.  Our actual yield of ammonia on a large scale amounting on an average to 32 kilos., equal to 70.6 lb. per ton of fuel, 125 tons of fuel will turn out 4 tons of sulphate of ammonia.  We thus consume 6.25 tons of fuel for every ton of sulphate obtained, or

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Scientific American Supplement, No. 717, September 28, 1889 from Project Gutenberg. Public domain.