line-spectra, and every chemical element possesses
in the incandescent gaseous state its own characteristic
lines of certain colour and certain refrangibility,
by means of which that element can be recognised.
To observe this you place a Bunsen burner opposite
the slit of the spectroscope, and introduce into its
colourless flame on the end of a platinum wire a little
of a volatile salt of the metal or element to be examined.
The flame of the lamp itself is often coloured with
a distinctiveness that is sufficient for a judgment
to be made with the aid of the naked eye alone, as
to the metal or element present. Thus soda and
its salts give a yellow flame, which is absolutely
yellow or monochromatic, and if you look through your
prism or spectroscope at it, you do not see a coloured
rainbow band or spectrum, as with daylight or gaslight,
but only one yellow double line, just where the yellow
would have been if the whole spectrum had been represented.
I think it is now plain that for the sake of observations
and exact discrimination, it is necessary to map out
our spectrum, and accordingly, in one of the tubes,
the third, the spectroscope is provided with a graduated
scale, so adjusted that when we look at the spectrum
we also see the graduations of the scale, and so our
spectrum is mapped; the lines marked out and named
with the large and small letters of the alphabet,
are certain of the prominent Fraunhofer’s lines
(see A, B, C, a, d,
etc., Fig. 16). We speak,
for example, of the soda yellow-line as coinciding
with D of the spectrum. These, then, are spectra
produced by luminous bodies.
The colouring matters and dyes, their solutions, and
the substances dyed with them, are not, of course,
luminous, but they do convert white light which strikes
upon or traverses them into coloured light, and that
is why they, in fact, appear either as coloured substances
or solutions. The explanation of the coloured
appearance is that the coloured substances or solutions
have the power to absorb from the white light that
strikes or traverses them, all the rays of the spectrum
but those which are of the colour of the substance
or solution in question, these latter being thrown
off or reflected, and so striking the eye of the observer.
Take a solution of Magenta, for example, and place
a light behind it. All the rays of that white
light are absorbed except the red ones, which pass
through and are seen. Thus the liquid appears
red. If a dyed piece be taken, the light strikes
it, and if a pure red, from that light all the rays
but red are absorbed, and so red light alone is reflected
from its surface. But this is not all with a dyed
fabric, for here the light is not simply reflected
light; part of it has traversed the upper layers of
that coloured body, and is then reflected from the
interior, losing a portion of its coloured rays by
absorption. This reflected coloured light is
always mixed with a certain amount of white light
reflected from the actual surface of the body before