of mordanting is not a practical man in the general
sense of the term, but a man of the highest scientific
attainments and standing, namely, Professor Liechti,
who, with his colleague Professor Suida, did probably
more than any other man to clear up much that heretofore
was cloudy in this region. We have seen that
with aluminium sulphate, basic salts are precipitated,
i.e. salts with such a predominance of appetite
for acids, or such quasi-acids as phenolic
substances, that if such bodies were present they would
combine with the basic parts of those precipitated
salts as soon as the latter were formed, and all would
be precipitated together as one complex compound.
Just such peculiar quasi-acid, or phenolic substances
are Alizarin, and most of the natural adjective dyestuffs,
the colouring principles of logwood, cochineal, Persian
berries, etc. Hence these substances will
be combined and carried down with such precipitated
basic salts. The complex compounds thus produced
are coloured substances known as lakes. For example,
if I take a solution containing basic sulphate of
alumina, prepared as I have already described, and
add to some Alizarin, and then heat the mixture, I
shall get a red lake of Alizarin and alumina precipitated.
If I had taken sulphate of iron instead of sulphate
of alumina, and proceeded in a similar manner, and
added Alizarin, I should have obtained a dark purple
lake. Now if you imagine these reactions going
on in a single fibre of a textile material, you have
grasped the theory and purpose of mordanting.
The textile fabric is drawn through the alumina solution
to fill the pores and tubes of the fabric; it is then
passed through a weak alkaline bath to basify or render
basic the aluminium salt in the pores; and then it
is finally carried into the dye-bath and heated there,
in order to precipitate the colour lake in the fibre.
The method usually employed to mordant woollen fabrics
consists in boiling them with weak solutions of the
metallic salts used as mordants, often with the addition
of acid salts, cream of tartar, and the like.
A partial decomposition of the metallic salts ensues,
and it is induced by several conditions: (1) The
dilution of the liquid; (2) the heating of the solution;
(3) the presence of the fibre, which itself tends
to cause the breaking up of the metallic salts into
less soluble basic ones. Thus it is not really
necessary to use basic aluminium sulphate for mordanting
wool, since the latter itself decomposes the normal
or neutral sulphate of alumina on heating, an insoluble
basic sulphate being precipitated in the fibres of
the wool. (4) The presence of other added substances,
as cream of tartar, etc. The best alumina
mordant is probably the acetate of alumina ("red liquor"),
and the best iron mordant, probably also the acetate
("iron liquor”) (see preceding lecture), because
the acetic acid is so harmless to the fibre, and is
easily driven off on steaming, etc. A further
reason is that from the solution of acetate of iron
or alumina, basic acetates are very easily precipitated
on heating, and are thus readily deposited in the
fibre.