calcium chloride (CaCl_{2}); and aluminium and iron,
triacid salts, for example, aluminium sulphate [Al_{2}(SO_{4})_{3}]
and iron (ferric) sulphate [Fe_{2}(SO_{4})_{3}].
Now in these triacid salts we can remove some of the
acid groups and substitute the elements of water, OH,
or hydroxyl, as it is called, for them. Such
salts, then, only partly saturated with acid, are
termed basic salts. Thus we have Al_{2}(OH)_{2}(SO_{4})_{2},
Al_{2}(OH)_{4}SO_{4}, as well as Al_{2}(SO_{4})_{3},
and we can get these basic salts by treating the normal
sulphate [Al_{2}(SO_{4})_{3}] with sufficient caustic
soda to remove the necessary quantities of sulphuric
acid. Now it is a curious thing that of these
aluminium sulphates the fully saturated one, Al_{2}(SO_{4})_{3},
is the most stable, for even on long boiling of its
solution in water it suffers no change, but the more
basic is the sulphate the less stable it becomes,
and so the more easily it decomposes on heating or
boiling its solution, giving a deposit or precipitate
of a still more basic sulphate, or of hydrated alumina
itself, Al_{2}(OH)_{6}, until we arrive at the salt
Al_{2}(SO_{4})_{2}(OH)_{2}, which is quite unstable
on boiling; Al_{2}(SO_{4})(OH)_{4} would be more unstable
still. This behaviour may be easily shown experimentally.
We will dissolve some “cake alum” or normal
sulphate of alumina, Al_{2}(SO_{4})_{3}, in water,
and boil some of the solution. No deposit or
precipitate is produced; the salt is stable.
To another portion of the solution we will add some
caustic soda, NaOH, in order to rob the normal sulphate
of alumina of some of its sulphuric acid. This
makes the sulphate of alumina basic, and the more
basic, the more caustic soda is added, the sodium (Na)
of the caustic soda combining with the SO_{4} of the
sulphate of alumina to form sulphate of soda (Na_{2}SO_{4}),
whilst the hydroxyl (OH) of the caustic soda takes
the position previously occupied by the SO_{4}.
But this increase of basicity also means decrease
of stability, for on boiling the solution, which now
contains a basic sulphate of alumina, a precipitate
is formed, a result which also follows if more caustic
soda is added, production of still more basic salts
or of hydrated alumina, Al_{2}(OH)_{6}, taking place
in either case.
Mordanting or Fixing Acid (Phenolic) Colours.—But
what has all this to do with mordanting? is possibly
now the inquiry. So much as this, that only such
unstable salts as I have just described, which decompose
and yield precipitates by the action on them of alkalis,
heat, the textile fibres themselves, or other agencies,
are suitable to act as true mordants. Hence,
generally, the sources or root substances of the best
and most efficient mordants are the metals of high
specific appetite or valency. I think we have
now got a clue to the principle of mordants and also
to the importance of a sound chemical knowledge in
dealing most effectively with them, and I may tell
you that the man who did most to elucidate the theory