atom or molecule several compound atoms or molecules
of an acid, we have the possibility of partial saturation,
and, perhaps, of several degrees of it, and also of
full saturation, which means combination to the full
extent of the powers of the base in question.
Also, with an acid capable of, or possessing a similar
large absorptive faculty for bases, we have possibilities
of the formation of salts of various degrees of basicity,
according to the smaller or larger degree of satisfaction
given to the molecule of such acid by the addition
of a base. We will now take as a simple case
that of hydrochloric acid (spirits of salt), which
is a monobasic acid, that is, its molecule is capable
of combining with only one molecule of a monoacid
base. Hydrochloric acid may be written, as its
name would indicate, HCl, and an addition even of excess
of such a base as caustic soda (written NaOH) would
only yield what is known as common salt or chloride
of sodium (NaCl), in which the metal sodium (Na) has
replaced the hydrogen (H) of the hydrochloric acid.
Now chloride of sodium when dissolved in water will
turn litmus neither blue nor red; it is therefore
neutral. Such simple, neutral, monobasic salts
are mostly very stable. By “stable”
we mean they possess considerable resistance to agencies,
that, in the case of other salts, effect decompositions
of those salts. Such other salts which are decomposed
more or less readily are termed “unstable,”
but the terms are of course only comparative.
Now let us consider a di- or bi-basic acid. Such
an one is vitriol or sulphuric acid (H_{2}SO_{4}).
The hydrogen atoms are in this case an index of the
basicity of the acid, and accordingly the fully saturated
sodium salt is Na_{2}SO_{4} or neutral, or better normal,
sulphate of soda. In like manner the fully saturated
salt of the dibasic acid, carbonic acid (H_{2}CO_{3}),
is Na_{2}CO_{3}, ordinary or normal carbonate of soda.
But we must observe that with these dibasic acids it
is possible, by adding insufficient alkali to completely
saturate them, to obtain salts in which only one hydrogen
atom of the acid is replaced by the metal of the base.
Thus sulphuric and carbonic acids yield NaHSO_{4},
acid sulphate or bisulphate of soda, and NaHCO_{3},
bicarbonate of soda, respectively. An example
of a tribasic acid is phosphoric acid, H_{3}PO_{4},
and here we may have three different classes of salts
of three various degrees of basicity or base-saturation.
We may have the first step of basicity due to combination
with soda, NaH_{2}PO_{4}, or monosodium phosphate,
the second step, Na_{3}HPO_{4}, or disodium phosphate,
and the third, and final step, Na_{3}PO_{4}, or trisodium
phosphate. Now let us turn to the varying degrees
of acidity, or rather the proportions of acid radicals
in salts, due to the varying appetites or combining
powers of bases. Sodium only forms simple monoacid
salts, as sodium chloride (NaCl), sodium sulphate
(Na_{2}SO_{4}); calcium forms diacid salts, e.g.