the base; such salts are termed acid salts. Bicarbonate
of soda is one of these acid salts, but so feeble is
carbonic acid in its acid properties and practical
evidences, that we shall see both monocarbonate or
“neutral” carbonate of soda and bicarbonate
or “acid” carbonate of soda show evidences
of, or, as chemists say, react with alkalinity towards
litmus. However, phenolphthalein, though reacting
alkaline with monocarbonate of soda, indicates the
acidity of the bicarbonate of soda, a thing which,
as I have just said, litmus will not do. We will
take two jars containing solution of monocarbonate
of soda, and in the first we will put some phenolphthalein
solution, and in the second, some litmus tincture.
The solution in the first jar turns rose coloured,
and in the second, blue, indicating in each case that
the solution is alkaline. If now, however, carbonic
acid be blown into the two solutions, that in the first
jar, containing the phenolphthalein, becomes colourless
as soon as the monocarbonate of soda is converted
into bicarbonate, and this disappearance of the rose
colour indicates acidity; the blue solution in the
jar containing litmus, on the other hand, is not altered
by blowing in carbonic acid. Furthermore, if
to the colourless solution containing phenolphthalein,
and which is acid towards that reagent, a little reddened
litmus is added, this is still turned blue, and so
still indicates the presence of alkali. We have,
therefore, in bicarbonate of soda a salt which behaves
as an acid to phenolphthalein and as an alkali to
litmus. Another extremely sensitive indicator
is the coal-tar dyestuff known as “Congo red”;
the colour changes produced by it are exactly the
inverse of those produced in the case of litmus, that
is, it gives a blue colour with acids and a red colour
with alkalis.
We have now learned that acids are as the antipodes
to alkalis or bases, and that the two may combine
to form products which may be neutral or may have
a preponderance either of acidity or of basicity—in
short, they may yield neutral, acid, or basic salts.
I must try to give you a yet clearer idea of these
three classes of salts. Now acids in general
have, as we have seen, what we may call a “chemical
appetite,” and each acid in particular has a
“specific chemical appetite” for bases,
that is, each acid is capable of combining with a
definite quantity of an individual base. The
terms “chemical appetite” and “specific
chemical appetite” are names I have coined for
your present benefit, but for which chemists would
use the words “affinity” and “valency”
respectively. Now some acids have a moderate specific
appetite, whilst others possess a large one, and the
same may be said of bases, and thus as an example
we may have mono-, di-, and tri-acid salts, or mono-,
di-, and tri-basic salts. In a tri-acid salt
a certain voracity of the base is indicated, and in
a tri-basic salt, of the acid. Again, with a base
capable of absorbing and combining with its compound