The Chemistry of Hat Manufacturing eBook

This eBook from the Gutenberg Project consists of approximately 158 pages of information about The Chemistry of Hat Manufacturing.

The Chemistry of Hat Manufacturing eBook

This eBook from the Gutenberg Project consists of approximately 158 pages of information about The Chemistry of Hat Manufacturing.
substratum which gradually comes to light, causing a greenish shade to at length appear.  If we examine under the microscope a pure unproofed fur fibre, its characteristic structure is quite visible.  Examination of an unproofed fibre dyed with logwood black shows again the same characteristic structure with the dye inside the fibre, colouring it a beautiful bluish-grey tint, the inner cellular markings being black.  A proofed fur fibre, on the other hand, when examined under the microscope, is seen to be covered with a kind of translucent glaze, which completely envelops it, and prevents the beautiful markings showing the scaly structure of the fibre from being seen.  Finally, if we examine microscopically a proofed fibre which has been dyed, or which we have attempted to dye, with logwood black, we find that the fibre presents an appearance similar to that of rope which has been drawn through some black pigment or black mud, and then dried.  It is quite plain that no lustrous appearance or good “finish” can be expected from such material.  Now how did the Continental hat manufacturers achieve their success, both as regards dyeing either with logwood black or with coal-tar colours, and also getting a high degree of “finish”?  They attained their object by rubbing the proofing varnish on the inside of the hat bodies, in some cases first protecting the outside with a gum-varnish soluble in water but resisting the lac-varnish rubbed inside.  Thus the proofing could never reach the outside.  On throwing the hat bodies, thus proofed by a logical and scientific process, into the dye-bath, the gums on the outer surface are dissolved and removed, and the dye strikes into a pure, clean fibre, capable of a high degree of finish.  This process, however, whilst very good for the softer hats used on the Continent, is not so satisfactory for the harder, stiffer headgear demanded in Great Britain.  What was needed was a process which would allow of a through-and-through proofing and stiffening, and also of satisfactory dyeing of the stiffened and proofed felt.  This was accomplished by a process patented in 1887 by Mr. F.W.  Cheetham, and called the “veneering” process.  The hat bodies, proofed as hard as usual, are thrown into a “bumping machine” containing hot water rendered faintly acid with sulphuric acid, and mixed with short-staple fur or wool, usually of a finer quality than that of which the hat bodies are composed.  The hot acid water promotes in a high degree the felting powers of the short-staple wool or fur, and, to a lesser extent, the thinly proofed ends of the fibres projecting from the surfaces of the proofed hat-forms.  Thus the short-staple wool or fur felts itself on to the fibres already forming part of the hat bodies, and a new layer of pure, unproofed wool or fur is gradually wrought on to the proofed surface.  The hat-forms are then taken out and washed, and can be dyed with the greatest ease and with excellent results, as will be seen from the accompanying illustration (see Fig. 15).  This successful invention emphasises the value of the microscope in the study of processes connected with textile fibres.  I would strongly advise everyone interested in hat manufacturing or similar industries to make a collection of wool and fur fibres, and mount them on microscope slides so as to form a kind of index collection for reference.

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The Chemistry of Hat Manufacturing from Project Gutenberg. Public domain.