the union of oxygen with sulphur dioxide and water;
the oxides of nitrogen combine with the oxygen of
the air present in the chambers, then give up this
oxygen to the sulphur dioxide and water or steam to
form sulphuric acid, again combine with more oxygen,
and so on. The exact processes or reactions are
of course much more complicated, but the above represents
what is practically the ultimate result. It is
evident that the gases leaving the last lead chamber
in which the formation of vitriol is effected, must
still contain nitrous fumes, and it becomes a matter
of importance to recover them, so that they can be
used over again. To effect this object, use is
made of the solubility of nitrous fumes in strong
vitriol. The gases from the last lead chamber
of the series are passed through what is called a
Gay-Lussac tower (the process was invented by the
eminent French chemist Gay-Lussac), which is a tower
made of lead, supported by a wooden framework, and
filled with coke or special stoneware packing, over
which strong vitriol is caused to flow. The vitriol
dissolves the nitrogen oxides, and so-called “nitrous
vitriol” flows out at the base of the tower.
The recovery of the nitrogen compounds from the nitrous
vitriol is effected in Glover towers (the invention
of John Glover of Newcastle), which also serve to
concentrate to some extent the weak acid produced in
the lead chambers, and to cool the hot gases from
the sulphur burners or pyrites kilns. The weak
chamber acid is mixed with the nitrous vitriol from
the Gay-Lussac tower, and the mixture is pumped to
the top of the Glover tower, which is of similar construction
to the Gay-Lussac tower, but is generally packed with
flints. This Glover tower is placed between the
sulphur burners or pyrites kilns and the first lead
chamber. The nitrous vitriol passing down the
tower meets the hot gases from the kilns, and a threefold
object is effected: (1) The nitrous fumes are
expelled from the nitrous vitriol, and are carried
into the chambers, to again play the part of oxygen-carriers;
(2) the weak chamber acid which was mixed with the
nitrous vitriol is concentrated by the hot kiln gases;
and (3) the hot gases themselves are cooled.
The acid from the Glover tower is purified by special
treatment—for example, the arsenic may be
removed, after precipitation with sulphuretted hydrogen,
in the form of insoluble arsenic sulphide,—and
the purified acid is concentrated by heating in glass
or platinum vessels.
A considerable amount of sulphuric acid is now made
by the so-called “contact process,” in
which sulphur dioxide and oxygen unite to form sulphuric
acid in presence of a heated “contact”
substance, usually some form of finely-divided platinum.
Nitric Acid.—This acid is usually
prepared by distilling a mixture of sodium nitrate
and vitriol in cast-iron retorts or pots, the nitric
acid being collected in stoneware vessels connected
one with another, or, as is more generally the case
at the present time, in condensing apparatus consisting
of stoneware pipes or coils cooled by water. The
effluent gases are passed through a scrubber in order
to free them from the last traces of acid before discharging
them into the atmosphere.