LECTURE V
ACIDS AND ALKALIS
Properties of Acids and Alkalis.—The name acids is given to a class of substances, mostly soluble in water, having an acid or sour taste, and capable of turning blue litmus solution red. All acids contain one or more atoms of hydrogen capable of being replaced by metals, and when such hydrogen atoms are completely replaced by metals, there result so-called neutral or normal salts, that is, neutral substances having no action on litmus solution. These salts can also be produced by the union of acids with equivalent quantities of certain metallic oxides or hydroxides, called bases, of which those soluble in water are termed alkalis. Alkalis have a caustic taste, and turn red litmus solution blue.
In order to explain what is called the law of equivalence, I will remind you of the experiment of the previous lecture, when a piece of bright iron, being placed in a solution of copper sulphate, became coated with metallic copper, an equivalent weight of iron meanwhile suffering solution as sulphate of iron. According to the same law, a certain weight of soda would always require a certain specific equivalent weight of an acid, say hydrochloric acid, to neutralise its alkaline or basic properties, producing a salt.
The specific gravities of acids and alkalis in solution are made use of in works, etc., as a means of ascertaining their strengths and commercial values. Tables have been carefully constructed, such that for every degree of specific gravity a corresponding percentage strength of acidity and alkalinity may be looked up. The best tables for this purpose are given in Lunge and Hurter’s Alkali-Makers’ Pocket-Book, but for ordinary purposes of calculation in the works or factory, a convenient relationship exists in the case of hydrochloric acid between specific gravity and percentage of real acid, such that specific gravity as indicated by Twaddell’s hydrometer directly represents percentage of real acid in any sample of hydrochloric acid.