solution, we get then a change which we might represent
thus: Copper sulphate, consisting of a combination
of copper oxide with sulphuric acid, yields with barium
chloride, which is a combination of barium and chlorine,
insoluble barium sulphate, a combination of barium
oxide with sulphuric acid, and soluble copper chloride,
a combination of copper and chlorine. This is
called a double interchange. Now these are a few
illustrations to show you what is meant by chemical
decompositions. One practical lesson, of course,
we may draw is this: We must have a care in dissolving
bluestone or copper sulphate, not to attempt it in
iron pans, and not to store or put verdigris into
iron vessels, or the iron will be acted upon, and
to some extent the copper salt will become contaminated
with iron. It will now be clear to you that, as
a solvent for bodies usually soluble in water, water
that is perfectly pure will be most suitable and not
likely to cause any deposition or precipitation through
chemical decompositions, for there are no salts or
other compounds in pure water to cause such changes.
Such pure water is called soft water. But the
term is only a comparative one, and water that is
not quite, but nearly pure—pure enough for
most practical purposes—is also called
soft water. Now rain is the purest form of natural
water, for it is a kind of distilled water. Water
rises in vapour from the ocean as from a still, and
the salt and other dissolved matters remain behind.
Meeting cold currents of air, the vapours condense
in rain, and fall upon the earth. After coming
in contact with the earth, the subsequent condition
of that water entirely depends upon the character,
as regards solubility or insolubility, of the substances
composing the strata or layers of earth upon which
it falls, and through which it sinks. If it meets
with insoluble rocks—for all rocks are not
insoluble—it remains, of course, pure and
soft, and in proportion as the constituents of rock
and soil are soluble, in that proportion does the
water become hard. We all know how dangerous acid
is in water, causing that water to act on many substances,
the iron of iron vessels, the lime in soil or rock,
etc., bringing iron and lime respectively into
solution. Now the atmosphere contains carbonic
acid, and carbonic acid occurs in the earth, being
evolved by decomposing vegetation, etc.
Carbonic acid is also soluble to a certain, though
not large extent, in water. As we shall see,
water charged with carbonic acid attacks certain substances
insoluble in pure water, and brings them into solution,
and thus the water soon becomes hard. About the
close of the last lecture, I said that lime is, to
a certain extent, soluble in cold water. The
solution is called lime-water; it might be called a
solution of caustic lime. When carbonic acid
gas first comes in contact with such a solution, chalk
or carbonate of lime, which is insoluble in water,
is formed, and the lime is thus precipitated as carbonate.