contains nitrogen. Thirdly, I will heat some fur
with soda-lime. Ammonia escapes, giving all the
reactions described under silk. Hence fur, wool,
etc., contain nitrogen. As regards proofs
of all three of these classes of fibres containing
carbon, hydrogen, and oxygen, the char they all leave
behind on heating in a closed vessel is the carbon
itself present. For the hydrogen and oxygen, a
perfectly dry sample of any of these fabrics is taken,
of course in quantity, and heated strongly in a closed
vessel furnished with a condensing worm like a still.
You will find all give you water as a condensate—the
vegetable fibre, acid water; the animal fibres, alkaline
water from the ammonia. The presence of water
proves both hydrogen and oxygen, since water is a
compound of these elements. If you put a piece
of potassium in contact with the water, the latter
will at once decompose, the potassium absorbing the
oxygen, and setting free the hydrogen as gas, which
you could collect and ignite with a match, when you
would find it would burn. That hydrogen was the
hydrogen forming part of your cotton, silk, or wool,
as the case might be. We must now attack the question
of sulphur. First, we prepare a little alkaline
lead solution (sodium plumbate) by adding caustic
soda to a solution of lead acetate or sugar of lead,
until the white precipitate first formed is just dissolved.
That is one of our reagents; the other is a solution
of a red-coloured salt called nitroprusside of sodium,
made by the action of nitric acid on sodium ferrocyanide
(yellow prussiate). The first-named is very sensitive
to sulphur, and turns black directly. To show
this, we take a quantity of flowers of sulphur, dissolve
in caustic soda, and add to the lead solution.
It turns black at once, because the sulphur unites
with the lead to form black sulphide of lead.
The nitroprusside, however, gives a beautiful crimson-purple
coloration. Now on taking a little cotton and
heating with the caustic alkaline lead solution, if
sulphur were present in that cotton, the fibre would
turn black or brown, for the lead would at once absorb
such sulphur, and form in the fibre soaked with it,
black sulphide of lead. No such coloration is
formed, so cotton does not contain sulphur. Secondly,
we must test silk. Silk contains nitrogen, like
wool, but does it contain sulphur? The answer
furnished by our tests is—no! since the
fibre is not coloured brown or black on heating with
the alkaline lead solution. Thirdly, we try some
white Berlin wool, so that we can easily see the change
of colour if it takes place. In the hot lead
solution the wool turns black, lead sulphide being
formed. On adding the nitroprusside solution to
a fresh portion of wool boiled with caustic soda,
to dissolve out the sulphur, a splendid purple coloration
is produced. Fur and hair would, of course, do
the same thing. Lead solutions have been used
for dyeing the hair black; not caustic alkaline solutions
like this, however. They would do something more
than turn the hair black—probably give rise
to some vigorous exercise of muscular power!
Still it has been found that even the lead solutions
employed have, through gradual absorption into the
system, whilst dyeing the hair black, also caused
colics and contractions of the limbs.