An amusing incident is told of a young man who painted his boat one night with a white paint in which lithopone was the pigment. On returning home the next afternoon after the boat had been exposed to sunlight all day, he was astonished to see that it was black. Being very much perturbed, he telephoned to the paint store, but the proprietor escaped a scathing lecture by having closed his shop at the usual hour. The young man telephoned in the morning and told the proprietor what had happened, but on being asked to make certain of the facts he went to the window and looked at his boat and behold! it was white. It had regained whiteness during the night but would turn black again during the day. Although pigments and dyes are not generally as peculiar as lithopone, much uncertainty is eliminated by systematic tests under constant, continuous, and controllable artificial light.
The sources of so-called chemical rays are numerous for laboratory work, but there is a need for highly efficient powerful producers of this kind of energy. In general the flame-arcs perhaps are foremost sources at the present time, with other kinds of carbon arcs and the quartz mercury-arc ranking next. One advantage of the mercury-arc is its constancy. Furthermore, for work with a single wave-length it is easy to isolate one of the spectral lines. The regular glass-tube mercury-arc is an efficient producer of the actinic rays and as a consequence has been extensively used in photographic work and in other photochemical processes. An excellent source for experimental work can be made easily by producing an arc between two small iron rods. The electric spark has served in much experimental work, but the total radiant energy from it is small. By varying the metals used for electrodes a considerable variety in the radiant energy is possible. This is also true of the electric arcs, and the flame-arcs may be varied widely by using different chemical compounds in the carbons.
There are other effects of light which have found applications but not in chemical reactions. For example, selenium changes its electrical resistance under the influence of light and many applications of this phenomenon have been made. Another group of light-effects forms a branch of science known as photo-electricity. If a spark-gap is illuminated by ultra-violet rays, the resistance of the gap is diminished. If an insulated zinc plate is illuminated by ultra-violet or violet rays, it will gradually become positively charged. These effects are due to the emission of electrons from the metal. Violet and ultra-violet rays will cause a colorless glass containing manganese to assume a pinkish color. The latter is the color which manganese imparts to glass and under the influence of these rays the color is augmented. Certain ultra-violet rays also ionize the air and cause the formation of ozone. This can be detected near a quartz mercury-arc, for example, by the characteristic odor.