Scientific American Supplement, No. 711, August 17, 1889 eBook

This eBook from the Gutenberg Project consists of approximately 137 pages of information about Scientific American Supplement, No. 711, August 17, 1889.

Scientific American Supplement, No. 711, August 17, 1889 eBook

This eBook from the Gutenberg Project consists of approximately 137 pages of information about Scientific American Supplement, No. 711, August 17, 1889.

Professional analytical chemists have hitherto given but little attention to these preparations, and the employment of experienced chemists in works is as yet far from general.  The testing of dyewood extracts in such a manner as to throw full light on their purity, the quality of raw material from which they are prepared, their exact commercial value their suitability for special purposes, and the proportion and nature of any adulterants they may contain, is of course a difficult and tedious task, and must be left to the expert who is in possession of authentic specimens prepared by himself of all the different extracts made from every variety and quality of raw materials, and who combines a thorough knowledge of experimental dyeing and printing with a large experience in the chemical investigation of these preparations.  But when the object of the testing is merely careful comparison of the sample in question with an original sample or previous deliveries, the case is much simplified, and comes within the scope of the general chemist or the laboratory attached to works.  A few years ago I recommended carefully conducted dyeing trials on woolen cloth mordanted with bichromate of potash as the best and simplest mode adapted to such cases, and my subsequent experience enables me to confirm that observation to the fullest extent.  Most of these extracts contain the coloring matter in two states, the developed and the undeveloped, and an oxidizing mordant such as bichromate of potash causes the latter as well as the former to enter completely into combination with a metallic base; whereas many of the other mordants, such as alumina or tin compounds, merely take up the developed portion of the coloring matter together with such small and variable proportions of the undeveloped as might undergo oxidation during the process of dyeing.  I would therefore suggest dyeing trials with alumina, tin, iron, etc., only as subsidiary tests indicating the suitability of an extract for certain special purposes, while recommending the trial with bichromate of potash as the one giving the best information respecting the actual strength of the extract in relation to the raw material from which it was obtained, and as giving a fair idea of the money value of the sample.  Cotton dyeing does not, as a general rule, afford a good means of assaying extracts, as it is generally done under conditions which do not admit of complete exhaustion of the dye bath, but it might often with advantage be resorted to as an additional trial throwing further light on the degree of oxidation or development of the coloring matter.  Printing trials are apt to give fallacious results unless the proportion of mordant is carefully adjusted to the amount of coloring matter present, and several trials with different proportions would be necessary to prevent erroneous conclusions.  For the trials with bichromate of potash on wool I would recommend pieces of cloth weighing about 150 grains, and the most suitable proportion

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Scientific American Supplement, No. 711, August 17, 1889 from Project Gutenberg. Public domain.