In the remainder of this paper I have been assisted by my son Bruce, who also assisted in the experiments that I have described. He has since been engaged on the trials on a manufacturing scale; and I ask you to permit him to read the concluding portion of the paper, in which he will describe the process, and what he has done.
The process referred to in the foregoing portion of the paper is a method employed for heating the liquor, whereby a chemical action is brought into play, with the results already mentioned. This method consists in passing the products of combustion of a furnace from a clear fire in a hot state through a still containing the ammoniacal liquor. The hot gases from the furnace impart their heat to the liquor, causing the volatilization of the condensed gases, and at the same time act chemically upon the liquor and evolved gases, so that ammonia and sulphuric acid are resulting products, in the compound state of sulphate of ammonia. The formation of the ammonia produced in the process is probably due to the decomposition of nitrogenous bodies contained in solution in the liquor—the sulphocyanide, for instance; the nitrogen being given off in the form of ammonia. Of the sulphuric acid produced, we look upon the sulphureted hydrogen as the source, also any sulphites existing in the liquor, which in their volatile state take up the atom of oxygen necessary for their conversion into sulphate.
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The apparatus used in working the process consists of a tower still, containing a number of superposed trays about 3 or 4 inches apart, with a lipped hole through the bottom of each at the side. The trays are so placed in the tower that the holes are at alternate sides. The liquor passes into the top of the still, and zigzags down through the series of trays, as in an ordinary Coffey still. The bottom tray differs from the rest; being much deeper, and having holes through it connecting it with the furnace, which is set immediately below it. The products of combustion of the fuel are caused to pass from the furnace up through the holes in the trays in the still, and, together with the gases evolved from the liquor, are directed into the saturator, where the sulphate of ammonia is obtained either in solution or in the crystalline state.
Where the process is at present being worked, an exhauster is used to draw the furnace gases through the still; but it might be advantageous to use a blower.
A small plant has been put in action at the gas works in Kilkenny and another on a larger scale, and differing somewhat in detail, here in Glasgow at the Alum and Ammonia Company’s works, where the liquor from the Tradeston Gas Works is converted. The trials on a working scale have only been made at both places within the past ten days; and, so far, nothing has appeared against the principle, though in certain of the details of construction some alterations are being made to improve it. The extra yield of salt from a given quantity of acid obtained in the experiments has been proved in practice, as also the absorption of the sulphureted hydrogen.