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originally charged negatively, it will be gradually discharged by this convective process. If it is not charged to start with, the electrons will still be liberated at the surface of the body, and this will acquire a positive charge. If the body is positively charged at first, we cannot discharge it by illumination.
It would be superfluous for me to speak here of the nature of electrons or of the various modes in which their presence may be detected. Suffice it to say, in further connection with the Hertz effect, that when projected among gaseous molecules the electron soon attaches itself to one of these. In other words, it ionises a molecule of the gas or confers its electric charge upon it. The gaseous molecule may even be itself disrupted by impact of the electron, if this is moving fast enough, and left bereft of an electron.
We must note that such ionisation may be regarded as conferring potential chemical properties upon the molecules of the gas and upon the substance whence the electrons are derived. Similar ionisation under electric forces enters, as we now believe, into all the chemical effects progressing in the galvanic cell, and, indeed, generally in ionised solutes.
An experiment will best illustrate the principles I wish to remind you of. A clean aluminium plate, carefully insulated by a sulphur support, is faced by a sheet of copper-wire-gauze placed a couple of centimetres away from it. The gauze is maintained at a high positive
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potential by this dry pile. A sensitive gold-leaf electroscope is attached to the aluminium plate, and its image thrown upon the screen. I now turn the light from this arc lamp upon the wire gauze, through which it in part passes and shines upon the aluminium plate. The electroscope at once charges up rapidly. There is a liberation of negative electrons at the surface of the aluminium; these, under the attraction of the positive body, are rapidly removed as ions, and the electroscope charges up positively.
Again, if I simply electrify negatively this aluminium plate so that the leaves of the attached electroscope diverge widely, and now expose it to the rays from the arc lamp, the charge, as you see, is very rapidly dissipated. With positive electrification of the aluminium there is no effect attendant on the illumination.
Thus from the work of Hertz and his successors we know that light, and more particularly what we call actinic light, is an effective means of setting free electrons from certain substances. In short, our photographic agent, light, has the power of expelling from certain substances the electron which is so potent a factor in most, if not in all, chemical effects. I have not time here to refer to the work of Elster and Geitel whereby they have shown that this action is to be traced to the electric force in the light wave, but must turn to the probable bearing of this phenomenon on the familiar facts of photography. I assume that the experiment I have shown you is the most