Scientific American Supplement, No. 613, October 1, 1887 eBook

This eBook from the Gutenberg Project consists of approximately 135 pages of information about Scientific American Supplement, No. 613, October 1, 1887.

Scientific American Supplement, No. 613, October 1, 1887 eBook

This eBook from the Gutenberg Project consists of approximately 135 pages of information about Scientific American Supplement, No. 613, October 1, 1887.
inquiry.  Not only had the number of distinct, well-established elementary bodies increased from fifty-three in 1837 to seventy in 1887, but the properties of these elements had been studied, and were now known with a degree of precision then undreamt of.  Had the atoms of our present elements been made to yield?  To this a negative answer must undoubtedly be given, for even the highest of terrestrial temperatures, that of the electric spark, had failed to shake any one of these atoms in two.  This was shown by the results with which spectrum analysis had enriched our knowledge.  Terrestrial analysis had failed to furnish favorable evidence; and, turning to the chemistry of the stars, the spectra of the white, which were presumably the hottest stars, furnished no direct evidence that a decomposition of any terrestrial atom had taken place; indeed, we learned that the hydrogen atom, as we know it here, can endure unscathed the inconceivably fierce temperature of stars presumably many times more fervent than our sun, as Sirius and Vega.  It was therefore no matter for surprise if the earth-bound chemist should for the present continue to regard the elements as the unalterable foundation stones upon which his science is based.

ATOMIC MOTION.

Passing to the consideration of atoms in motion, while Dalton and Graham indicated that they were in a continual state of motion, we were indebted to Joule for the first accurate determination of the rate of that motion.  Clerk-Maxwell had calculated that a hydrogen molecule, moving at the rate of seventy miles per minute, must, in one second of time, knock against others no fewer than eighteen thousand million times.  This led to the reflection that in nature there is no such thing as great or small, and that the structure of the smallest particle, invisible even to our most searching vision, may be as complicated as that of any one of the heavenly bodies which circle round our sun.  How did this wonderful atomic motion affect their chemistry?

ATOMIC COMBINATION.

Lavoisier left unexplained the dynamics of combustion; but in 1843, before the chemical section of the association meeting at Cork, Dr. Joule announced the discovery which was to revolutionize modern science, namely, the determination of the mechanical equivalent of heat.  Every change in the arrangement of the particles he found was accompanied by a definite evolution or an absorption of heat.  Heat was evolved by the clashing of the atoms, and this amount was fixed and definite.  Thus to Joule we owe the foundation of chemical dynamics and the basis of thermal chemistry.  It was upon a knowledge of the mode of arrangement of atoms, and on a recognition of their distinctive properties, that the superstructure of modern organic chemistry rested.  We now assumed on good grounds that the atom of each element possessed distinct capabilities of combination.  The knowledge of the mode in which the atoms in the molecule are arranged had given to organic chemistry an impetus which had overcome many experimental obstacles, and organic chemistry had now become synthetic.

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Scientific American Supplement, No. 613, October 1, 1887 from Project Gutenberg. Public domain.