hydrogen separately. These exceptions probably
arise from the circumstance that the energy of chemical
action is absorbed to a greater or less degree in effecting
molecular changes, as, for example, the combustion
of 1 pound of nitrogen to form protoxide of nitrogen
results in the absorption of 1,157 units of heat.
Berthelot states, as one of the fundamental principles
of thermochemistry, “that the quantity of heat
evolved is the measure of the sum of the chemical
and physical work accomplished in the reaction”;
and such a law will no doubt account for the phenomena
above noted. The equivalent heat of combustion
of the compounds we have practically to deal with
has been experimentally determined, and therefore
constitutes a secure basis on which to establish calculations
of the caloric value of fuel; and in doing so, with
respect to substances composed of carbon, hydrogen,
and oxygen, it is convenient to reduce the hydrogen
to its heat-producing equivalent of carbon. The
heat of combustion of hydrogen being 62,032 units,
that of carbon 14,544 units, it follows that 4.265
times the weight of hydrogen will represent an equivalent
amount of carbon. With respect to the oxygen,
it is found that it exists in combination with the
hydrogen in the form of water, and, being combined
already, abstracts its combining equivalent of hydrogen
from the efficient ingredients of the fuel; and hence
hydrogen, to the extent of 1/8 of the weight of the
oxygen, must be deducted. The general formula
then becomes:
Heat of
combustion = 14,544 {C + 4.265 (H-(O/8))},
and water evaporated from and at 212 deg., taking
966 units as the heat necessary to evaporate 1 pound
of water,
lb. evaporated
= 15.06 {C + 4.265 (H-(O/8))},
carbon, hydrogen, and oxygen being taken at their
weight per cent. in the fuel. Strictly speaking,
marsh gas should be separately determined. It
often happens that available energy is not in a form
in which it can be applied directly to our needs.
The water flowing down from the mountains in the neighborhood
of the Alpine tunnels was competent to provide the
power necessary for boring through them, but it was
not in a form in which it could be directly applied.
The kinetic energy of the water had first to be changed
into the potential energy of air under pressure, then,
in that form, by suitable mechanism, it was used with
signal success to disintegrate and excavate the hard
rock of the tunnels. The energy resulting from
combustion is also incapable of being directly transformed
into useful motive power; it must first be converted
into potential force of steam or air at high temperature
and pressure, and then applied by means of suitable
heat engines to produce the motions we require.
It is probably to this circumstance that we must attribute
the slowness of the human race to take advantage of
the energy of combustion. The history of the
steam engine hardly dates back 200 years, a very small
fraction of the centuries during which man has existed,
even since historic times.