the absolute zero of temperature. At one end
erect an ordinate, upon which set off T = 3,777 deg.,
the temperature of the furnace. At 849 deg. =
t, on the scale of temperature, draw a line
parallel to the base, and mark on it a length proportional
to the heating surface of the boiler; join T by a
diagonal with the extremity of this line, and drop
a perpendicular on to the zero line. The temperature
of the water in the boiler being uniform, the ordinates
bounded by the sloping line, and by the line, t,
will at any point be approximately proportional to
the rate of transmission of heat, and the shaded area
above t will be proportional to the quantity
of heat imparted to the water. Join T by another
diagonal with extremity of the heating surface on the
zero line, then the larger triangle, standing on the
zero line, will represent the whole of the heat of
combustion, and the ratio of the two triangles will
be as the lengths of their respective bases, that
is, as (T — t) / T, which is the expression
we have already used. The heating surface was
220 square feet, and it was competent to transmit
the energy developed by 41 lb. of coal consumed per
hour = 12,819 u. x 41 u. = 525,572 units, equal to
an average of 2,389 units per square foot per hour;
this value will correspond to the mean pressure in
an ordinary diagram, for it is a measure of the energy
with which molecular motion is transferred from the
heated gases to the boiler-plate, and so to the water.
The mean rate of transmission, multiplied by the area
of heating surface, gives the area of the shaded portion
of the figure, which is the total work which should
have been done, that is to say, the work of evaporating
544 lb. of water per hour. The actual work done,
however, was only 485 lb. To give the speculations
we have indulged in a practical turn, it will be necessary
to examine in detail the terms of Carnot’s formula.
Carnot labored under great disadvantages. He
adhered to the emission theory of heat; he was unacquainted
with its dynamic equivalent; he did not know the reason
of the difference between the specific heat of air
at constant pressure and at constant volume, the idea
of an absolute zero of temperature had not been broached;
but the genius of the man, while it made him lament
the want of knowledge which he felt must be attainable,
also enabled him to penetrate the gloom by which he
was surrounded, and enunciate propositions respecting
the theory of heat engines, which the knowledge we
now possess enables us to admit as true. His
propositions are:
1. The motive power of heat is independent of the agents employed to develop it, and its quantity is determined solely by the temperature of the bodies between which the final transfer of caloric takes place.
2. The temperature of the agent must in the first instance be raised to the highest degree possible in order to obtain a great fall of caloric, and as a consequence a large production of motive power.