Nitro-Explosives: A Practical Treatise eBook

This eBook from the Gutenberg Project consists of approximately 310 pages of information about Nitro-Explosives.

Nitro-Explosives: A Practical Treatise eBook

This eBook from the Gutenberg Project consists of approximately 310 pages of information about Nitro-Explosives.

I. = 144.4; II. = 153.3; III. = 154.4 grms.; 100 grms. of fibre being used in all three cases.

Duration of exposure, thirty minutes at 18 deg.  C.

The nitrogen was determined in the products, and equalled 10.5 per cent.  Theory for C_{12}H_{15}O_{6}(NO_{3})_{3} = 9.5 per cent. and for C_{12}H_{15}O_{6}(NO_{3})_{4} = 11.5 per cent.  These nitrates resemble those of cellulose, and are in all essential points nitrates of ligno-cellulose.

Muehlhaeusen obtained a much lower yield, and probably, as pointed out by Cross and Bevan, a secondary decomposition took place, and his products, therefore, probably approximate to the derivatives of cellulose rather than to those of ligno-cellulose, the more oxidisable, non-cellulose, or lignone constituents having been decomposed.  In fact, he regards his product as cellulose penta-nitrate (C_{12}H_{16}O_{5}(ONO_{2})_{5}).  The Chemiker Zeitung, xxi., p. 163, contains a further paper by Muehlhaeusen on the explosive nitro-jute.  After purifying the jute-fibre by boiling it with a 1 per cent. solution of sodium carbonate, and washing with water, he treated 1 part of the purified jute with 15 parts of nitro-sulphuric acid, and obtained the following results with different proportions of nitric to sulphuric acids:—­

Yield  Ignition Nitrogen.
per cent.   Point. 
Experiment  I.—­ 1.  HNO_{3}  1.  H_{2}SO_{4}  129.5   170 deg.  C.   11.96%
"      II.       "       2.    "         132.2   167 deg.  C.   12.15%
"     III.       "       3.    "         135.8   169 deg.  C.   11.91%

An experiment made with fine carded jute and the same mixture of acids as in No.  II. gave 145.4 per cent. nitro-jute, which ignited at 192 deg.  C., and contained 12 per cent. nitrogen.  This explosive is not at present manufactured upon the large scale, and Messrs Cross and Bevan are of opinion that there is no very obvious advantage in the use of lignified textile fibre as raw materials for explosive nitrates, seeing that a large number of raw materials containing cellulose (chiefly as cotton) can be obtained at a cheaper rate, and yield also 150 to 170 per cent. of explosive material when nitrated, and are in many ways superior to the products obtained hitherto from jute.

Nitro-mannite is formed by the action of nitric acid on mannite, a hex-acid alcohol closely related to sugar.  It occurs abundantly in manna, which is the partly dried sap of the manna-ash (Fraxinus ornus).  It is formed in the lactic acid fermentation of sugar, and by the action of nascent hydrogen on glucose and cellulose, or on invert sugar.  Its formula is C_{6}H_{8}(OH)_{6} and that of nitro-mannite C_{6}H_{8}(NO_{3})_{6}.  Mannite crystallises in needles or rhombic prisms, which are soluble in water and alcohol, and have a sweet taste.  Nitro-mannite forms white needle-shaped crystals, insoluble in water, but soluble in ether or alcohol.  When rapidly heated, they ignite at about 374 deg.  F., and explode at about 590 deg.  F. It is more susceptible to friction and percussion than nitro-glycerine, and unless pure it is liable to spontaneous decomposition.  It is considered as the nitric ether of the hexatomic alcohol mannite.  It is formed by the action of a mixture of nitric and sulphuric acids upon mannite—­

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