Blasting gelatine (90 per cent. nitro-glycerine and
nitro-cellulose) 392 Ammonite (60 per cent.
Am(NO_{3}) and 10 per cent. nitro-naphthalene) 310
Gelignite (60 per cent. nitro-gelatine and gun-cotton)
306 Roburite (AmNO_{3} and chloro-nitro-benzol)
294 No. 1 dynamite (75 per
cent. nitro-gelatine) 264
Stonite (68 per cent. nitro-gelatine and 32 per cent.
wood-meal) 253 Gun-cotton
234 Tonite
(gun-cotton and nitrates)
223 Carbonite (25 per cent. nitro-gelatine,
40 per cent. wood-meal,
and 30 per cent. nitrates)
198
Securite (KNO_{3} and nitro-benzol)
183 Gunpowder
143
Calculation of the Volume of Gas Evolved in an Explosive Reaction.—The volume of gas evolved in an explosive reaction may be calculated, but only when they are simple and stable products, such calculations being made at 0 deg. and 760 mm. Let it be required, for example, to determine the volume of gas evolved by 1 gram-molecule of nitro-glycerine. The explosive reaction of nitro-glycerine may be represented by the equation.
C_{3}H_{5}O_{3}(NO_{2})_{3} = 3CO_{2} + 2-1/2H_{2}O + 1-1/2N_{2} + 1/4O_{2} By weight 227 = 132 + 45 + 42 + 8 By volume 2 = 3 + 2-1/2 + 1-1/2 + 1/4
The weights of the several products of the above reactions are calculated by multiplying their specific gravities by the weight of 1 litre of hydrogen at 0 deg. C. and 760 mm. (0.0896 grm). Thus,
One litre of CO_{2} = 22 x .0896 = 1.9712 grm.
" H_{2}O = 9
x " = 0.8064 "
" N_{2} = 14
x " = 1.2544 "
" O_{2} = 16
x " = 1.4336 "
The volume of permanent gases at 0 deg. and 760 mm. is constant, and assuming the gramme as the unit of mass, is found to be 22.32 litres. Thus:—
Volume of 44 of CO_{2}, at 0 deg. and 760 mm. = 44/1.9712
= 22.32 litres.
18
" H_{2}O " " = 18/0.8044 = 22.32
"
28
" N_{2} " " = 28/1.2544 = 22.32
"
32
" O_{2} " " = 32/1.4366 = 22.32
"
Therefore
132 grms. of CO_{2} at 0 deg. C and 760 mm. =
22.32 x 3 = 66.96 litres. 45 " H_{2}O
" " = 22.32 x 2-1/2 = 55.80 " 42
" N_{2} " " = 22.32 x 1-1/2
= 33.48 "
8 " O_{2} " "
= 22.32 x 1/4 = 5.58 "
____________
161.82
"
Therefore 1 gram-molecule or 227 grms. of nitro-glycerine
when exploded, produces 161.82 litres of gas at 0
deg. C and 760 mm.