It would certainly be contrary to all experience, and even to common sense itself, to suppose that in dissolved chloride of sodium there is really free sodium, if we suppose these atoms of sodium to be absolutely identical with ordinary atoms. But there is a great difference. In the one case the atoms are electrified, and carry a relatively considerable positive charge, inseparable from their state as ions, while in the other they are in the neutral state. We may suppose that the presence of this charge brings about modifications as extensive as one pleases in the chemical properties of the atom. Thus the hypothesis will be removed from all discussion of a chemical order, since it will have been made plastic enough beforehand to adapt itself to all the known facts; and if we object that sodium cannot subsist in water because it instantaneously decomposes the latter, the answer is simply that the sodium ion does not decompose water as does ordinary sodium.
Still, other objections might be raised which could not be so easily refuted. One, to which chemists not unreasonably attached great importance, was this:—If a certain quantity of chloride of sodium is dissociated into chlorine and sodium, it should be possible, by diffusion, for example, which brings out plainly the phenomena of dissociation in gases, to extract from the solution a part either of the chlorine or of the sodium, while the corresponding part of the other compound would remain. This result would be in flagrant contradiction with the fact that, everywhere and always, a solution of salt contains strictly the same proportions of its component elements.
M. Arrhenius answers to this that the electrical forces in ordinary conditions prevent separation by diffusion or by any other process. Professor Nernst goes further, and has shown that the concentration currents which are produced when two electrodes of the same substance are plunged into two unequally concentrated solutions may be interpreted by the hypothesis that, in these particular conditions, the diffusion does bring about a separation of the ions. Thus the argument is turned round, and the proof supposed to be given of the incorrectness of the theory becomes a further reason in its favour.
It is possible, no doubt, to adduce a few other experiments which are not very favourable to M. Arrhenius’s point of view, but they are isolated cases; and, on the whole, his theory has enabled many isolated facts, till then scattered, to be co-ordinated, and has allowed very varied phenomena to be linked together. It has also suggested—and, moreover, still daily suggests—researches of the highest order.