From these comparisons, and from other important researches, among which should be particularly mentioned those of Mr S. Young and M. Mathias, it results that the laws of corresponding states have not, unfortunately, the degree of generality which we at first attributed to them, but that they are satisfactory when applied to certain groups of bodies.[7]

[Footnote 7:  Mr Preston thus puts it:  “The law [of corresponding states] seems to be not quite, but very nearly true for these substances [i.e. the halogen derivatives of benzene]; but in the case of the other substances examined, the majority of these generalizations were either only roughly true or altogether departed from” (Theory of Heat, London, 1904, p. 514.)—­ED.]

If in the study of the statics of a simple fluid the experimental results are already complex, we ought to expect much greater difficulties when we come to deal with mixtures; still the problem has been approached, and many points are already cleared up.

Mixed fluids may first of all be regarded as composed of a large number of invariable particles.  In this particularly simple case M. Van der Waals has established a characteristic equation of the mixtures which is founded on mechanical considerations.  Various verifications of this formula have been effected, and it has, in particular, been the object of very important remarks by M. Daniel Berthelot.

It is interesting to note that thermodynamics seems powerless to determine this equation, for it does not trouble itself about the nature of the bodies obedient to its laws; but, on the other hand, it intervenes to determine the properties of coexisting phases.  If we examine the conditions of equilibrium of a mixture which is not subjected to external forces, it will be demonstrated that the distribution must come back to a juxtaposition of homogeneous phases; in a given volume, matter ought so to arrange itself that the total sum of free energy has a minimum value.  Thus, in order to elucidate all questions relating to the number and qualities of the phases into which the substance divides itself, we are led to regard the geometrical surface which for a given temperature represents the free energy.

I am unable to enter here into the detail of the questions connected with the theories of Gibbs, which have been the object of numerous theoretical studies, and also of a series, ever more and more abundant, of experimental researches.  M. Duhem, in particular, has published, on the subject, memoirs of the highest importance, and a great number of experimenters, mostly scholars working in the physical laboratory of Leyden under the guidance of the Director, Mr Kamerlingh Onnes, have endeavoured to verify the anticipations of the theory.

We are a little less advanced as regards abnormal substances; that is to say, those composed of molecules, partly simple and partly complex, and either dissociated or associated.  These cases must naturally be governed by very complex laws.  Recent researches by MM.  Van der Waals, Alexeif, Rothmund, Kuenen, Lehfeld, etc., throw, however, some light on the question.