It is, consequently, possible to cause condensation on negative centres only, and to study separately the phenomena produced by the two kinds of ions. It can thus be verified that they really bear charges equal in absolute value, and these charges can even be estimated, since we already know the number of drops. This estimate can be made, for example, by comparing the speed of the fall of a mist in fields of different values, or, as did J.J. Thomson, by measuring the total quantity of electricity liberated throughout the gas.
At the degree of approximation which such experiments imply, we find that the charge of a drop, and consequently the charge borne by an ion, is sensibly 3.4 x 10^{-10} electrostatic or 1.1 x 10^{-20} electromagnetic units. This charge is very near that which the study of the phenomena of ordinary electrolysis leads us to attribute to a univalent atom produced by electrolytic dissociation.
Such a coincidence is evidently very striking; but it will not be the only one, for whatever phenomenon be studied it will always appear that the smallest charge we can conceive as isolated is that mentioned. We are, in fact, in presence of a natural unit, or, if you will, of an atom of electricity.
We must, however, guard against the belief that the gaseous ion is identical with the electrolytic ion. Sensible differences between those are immediately apparent, and still greater ones will be discovered on closer examination.
As M. Perrin has shown, the ionisation produced by the X-rays in no way depends on the chemical composition of the gas; and whether we take a volume of gaseous hydrochloric acid or a mixture of hydrogen and chlorine in the same condition, all the results will be identical: and chemical affinities play no part here.
We can also obtain other information regarding ions: we can ascertain, for instance, their velocities, and also get an idea of their order of magnitude.
By treating the speeds possessed by the liberated charges as components of the known speed of a gaseous current, Mr Zeleny measures the mobilities, that is to say, the speeds acquired by the positive and negative charges in a field equal to the electrostatic unit. He has thus found that these mobilities are different, and that they vary, for example, between 400 and 200 centimetres per second for the two charges in dry gases, the positive being less mobile than the negative ions, which suggests the idea that they are of greater mass.[30]
[Footnote 30: A full account of these experiments, which were executed at the Cavendish Laboratory, is to be found in Philosophical Transactions, A., vol. cxcv. (1901), pp. 193 et seq.—ED.]