M. Righi has ably demonstrated that ionised gas does not obey the law of Ohm by an experiment very paradoxical in appearance. He found that, the greater the distance of the two electrode plates from each, the greater may be, within certain limits, the intensity of the current. The fact is very clearly interpreted by the theory of ionisation, since the greater the length of the gaseous column the greater must be the number of ions liberated.
One of the most striking characteristics of ionised gases is that of discharging electrified conductors. This phenomenon is not produced by the departure of the charge that these conductors may possess, but by the advent of opposite charges brought to them by ions which obey the electrostatic attraction and abandon their own electrification when they come in contact with these conductors.
This mode of regarding the phenomena is extremely convenient and eminently suggestive. It may, no doubt, be thought that the image of the ions is not identical with objective reality, but we are compelled to acknowledge that it represents with absolute faithfulness all the details of the phenomena.
Other facts, moreover, will give to this hypothesis a still greater value; we shall even be able, so to speak, to grasp these ions individually, to count them, and to measure their charge.
Sec. 2. THE CONDENSATION OF WATER-VAPOUR BY IONS
If the pressure of a vapour—that of water, for instance—in the atmosphere reaches the value of the maximum pressure corresponding to the temperature of the experiment, the elementary theory teaches us that the slightest decrease in temperature will induce a condensation; that small drops will form, and the mist will turn into rain.
In reality, matters do not occur in so simple a manner. A more or less considerable delay may take place, and the vapour will remain supersaturated. We easily discover that this phenomenon is due to the intervention of capillary action. On a drop of liquid a surface-tension takes effect which gives rise to a pressure which becomes greater the smaller the diameter of the drop.
Pressure facilitates evaporation, and on more closely examining this reaction we arrive at the conclusion that vapour can never spontaneously condense itself when liquid drops already formed are not present, unless forces of another nature intervene to diminish the effect of the capillary forces. In the most frequent cases, these forces come from the dust which is always in suspension in the air, or which exists in any recipient. Grains of dust act by reason of their hygrometrical power, and form germs round which drops presently form. It is possible to make use, as did M. Coulier as early as 1875, of this phenomenon to carry off the germs of condensation, by producing by expansion in a bottle containing a little water a preliminary mist which purifies the air. In subsequent experiments it will be found almost impossible to produce further condensation of vapour.