Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

416.  The relation, under this law, of the conducting power for electricity to that for heat, is very remarkable, and seems to imply a natural dependence of the two.  As the solid becomes a fluid, it loses almost entirely the power of conduction for heat, but gains in a high degree that for electricity; but as it reverts hack to the solid state, it gains the power of conducting heat, and loses that of conducting electricity.  If, therefore, the properties are not incompatible, still they are most strongly contrasted, one being lost as the other is gained.  We may hope, perhaps, hereafter to understand the physical reason of this very extraordinary relation of the two conducting powers, both of which appear to be directly connected with the corpuscular condition of the substances concerned.

417.  The assumption of conducting power and a decomposable condition by liquefaction, promises new opportunities of, and great facilities in, voltaic decomposition.  Thus, such bodies as the oxides, chlorides, cyanides, sulpho-cyanides, fluorides, certain vitreous mixtures, &c. &c., may be submitted to the action of the voltaic battery under new circumstances; and indeed I have already been able, with ten pairs of plates, to decompose common salt, chloride of magnesium, borax, &c. &c., and to obtain sodium, magnesium, boron, &c., in their separate states.

S 10. On Conducting Power generally.[A]

  [A] In reference to this S refer to 983 in series viii., and the
  results connected with it.—­Dec. 1838.

418.  It is not my intention here to enter into an examination of all the circumstances connected with conducting power, but to record certain facts and observations which have arisen during recent inquiries, as additions to the general stock of knowledge relating to this point of electrical science.

419.  I was anxious, in the first place, to obtain some idea of the conducting power of ice and solid salts for electricity of high tension (392.), that a comparison might be made between it and the large accession of the same power gained upon liquefaction.  For this purpose the large electrical machine (290.) was brought into excellent action, its conductor connected with a delicate gold-leaf electrometer, and also with the platina inclosed in the ice (383.), whilst the tin case was connected with the discharging train (292.).  On working the machine moderately, the gold leaves barely separated; on working it rapidly, they could be opened nearly two inches.  In this instance the tin case was five-eighths of an inch in width; and as, after the experiment, the platina plate was found very nearly in the middle of the ice, the average thickness of the latter had been five-sixteenths of an inch, and the extent of surface of contact with tin and platina fourteen square inches (384.).  Yet, under these circumstances, it was but just able to conduct the small quantity of electricity which this machine could evolve (371.), even when of a tension competent to open the leaves two inches; no wonder, therefore, that it could not conduct any sensible portion of the electricity of the troughs (384.), which, though almost infinitely surpassing that of the machine in quantity, had a tension so low as not to be sensible to an electrometer.

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