1741. It is easily conceivable that the same force which causes local action between two free particles shall produce current force if one of the particles is previously in combination, forming part of an electrolyte (923. 1738.). Thus a particle of zinc, and one of oxygen, when in presence of each other, exert their inductive forces (1740.), and these at last rise up to the point of combination. If the oxygen be previously in union with hydrogen, it is held so combined by an analogous exertion and arrangement of the forces; and as the forces of the oxygen and hydrogen are for the time of combination mutually engaged and related, so when the superior relation of the forces between the oxygen and zinc come into play, the induction of the former or oxygen towards the metal cannot be brought on and increased without a corresponding deficiency in its induction towards the hydrogen with which it is in combination (for the amount of force in a particle is considered as definite), and the latter therefore has its force turned towards the oxygen of the next particle of water; thus the effect may be considered as extended to sensible distances, and thrown into the condition of static induction, which being discharged and then removed by the action of other particles produces currents.
1742. In the common voltaic battery, the current is occasioned by the tendency of the zinc to take the oxygen of the water from the hydrogen, the effective action being at the place where the oxygen leaves the previously existing electrolyte. But Schoenbein has arranged a battery in which the effective action is at the other extremity of this essential part of the arrangement, namely, where oxygen goes to the electrolyte[A]. The first may be considered as a case where the current is put into motion by the abstraction of oxygen from hydrogen, the latter by that of hydrogen from oxygen. The direction of the electric current is in both cases the same, when referred to the direction in which the elementary particles of the electrolyte are moving (923. 962.), and both are equally in accordance with the hypothetical view of the inductive action of the particles just described (1740.).
[A] Philosophical Magazine, 1838, xii.
225, 315. also De la Rive’s
results with peroxide of manganese.
Annales de Chimie, 1836, lxi. p.
40.—Dec. 1838.
1743. In such a view of voltaic excitement, the action of the particles may be divided into two parts, that which occurs whilst the force in a particle of oxygen is rising towards a particle of zinc acting on it, and falling towards the particle of hydrogen with which it is associated (this being the progressive period of the inductive action), and that which occurs when the change of association takes place, and the particle of oxygen leaves the hydrogen and combines with the zinc. The former appears to be that which produces the current, or if there be no current, produces the state of tension at the termination of the battery; whilst the latter, by terminating for the time the influence of the particles which have been active, allows of others coming into play, and so the effect of current is continued.