1649. Hence has arisen the desire of estimating this velocity either directly or by some effect dependent on it; and amongst the endeavours to do this correctly, may be mentioned especially those of Dr. Watson[A] in 1748, and of Professor Wheatstone[B] in 1834; the electricity in the early trials being supposed to travel from end to end of the arrangement, but in the later investigations a distinction occasionally appearing to be made between the transmission of the effect and of the supposed fluid by the motion of whose particles that effect is produced.
[A] Philosophical Transactions, 1748.
[B] Ibid. 1834, p. 583.
1650. Electrolytic action has a remarkable bearing upon this question of the velocity of the current, especially as connected with the theory of an electric fluid or fluids. In it there is an evident transfer of power with the transfer of each particle of the anion or cathion present, to the next particles of the cathion or anion; and as the amount of power is definite, we have in this way a means of localizing as it were the force, identifying it by the particle and dealing it out in successive portions, which leads, I think, to very striking results.
1651. Suppose, for instance, that water is undergoing decomposition by the powers of a voltaic battery. Each particle of hydrogen as it moves one way, or of oxygen as it moves in the other direction, will transfer a certain amount of electrical force associated with it in the form of chemical affinity (822. 852. 918.) onwards through a distance, which is equal to that through which the particle itself has moved. This transfer will be accompanied by a corresponding movement in the electrical forces throughout every part of the circuit formed (1627. 1634.), and its effects may be estimated, as, for instance, by the heating of a wire (853.) at any particular section of the current however distant. If the water be a cube of an inch in the side, the electrodes touching, each by a surface of one square inch, and being an inch apart, then, by the time that a tenth of it, or 25.25 grs., is decomposed, the particles of oxygen and hydrogen throughout the mass may be considered as having moved relatively to each other in opposite directions, to the amount of the tenth of an inch; i.e. that two particles at first in combination will after the motion be the tenth of an inch apart. Other motions which occur in the fluid will not at all interfere with this result; for they have no power of accelerating or retarding the electric discharge, and possess in fact no relation to it.