1421.  The characters of the electric spark in different gases vary, and the variation may be due simply to the effect of the heat evolved at the moment.  But it may also be due to that specific relation of the particles and the electric forces which I have assumed as the basis of a theory of induction; the facts do not oppose such a view; and in that view the variation strengthens the argument for molecular action, as it would seem to show the influence of the latter in every part of the electrical effect (1423. 1454.).

1422.  The appearances of the sparks in different gases have often been observed and recorded[A], but I think it not out of place to notice briefly the following results; they were obtained with balls of brass, (platina surfaces would have been better,) and at common pressures.  In air, the sparks have that intense light and bluish colour which are so well known, and often have faint or dark parts in their course, when the quantity of electricity passing is not great.  In nitrogen, they are very beautiful, having the same general appearance as in air, but have decidedly more colour of a bluish or purple character, and I thought were remarkably sonorous.  In oxygen, the sparks were whiter than in air or nitrogen, and I think not so brilliant.  In hydrogen, they had a very fine crimson colour, not due to its rarity, for the character passed away as the atmosphere was rarefied (1459.)[B].  Very little sound was produced in this gas; but that is a consequence of its physical condition[C].  In carbonic acid gas, the colour was similar to that of the spark in air, but with a little green in it:  the sparks were remarkably irregular in form, more so than in common air:  they could also, under similar circumstances as to size of ball, &c., be obtained much longer than in air, the gas showing a singular readiness to cause the discharge in the form of spark.  In muriatic acid gas, the spark was nearly white:  it was always bright throughout, never presenting those dark parts which happen in air, nitrogen, and some other gases.  The gas was dry, and during the whole experiment the surface of the glass globe within remained quite dry and bright.  In coal gas, the spark was sometimes green, sometimes red, and occasionally one part was green and another red:  black parts also occur very suddenly in the line of the spark, i.e. they are not connected by any dull part with bright portions, but the two seem to join directly one with the other.

  [A] See Van Marum’s description of the Teylerian machine, vol. i. p.
  112, and vol. ii. p. 196; also Ency.  Britan., vol. vi., Article
  Electricity, pp. 505, 507.

  [B] Van Marum says they are about four times as large in hydrogen as
  in air. vol. i. p. 122.

  [C] Leslie.  Cambridge Phil.  Transactions, 267.

1423.  These varieties of character impress my mind with a feeling, that they are due to a direct relation of the electric powers to the particles of the dielectric through which the discharge occurs, and are not the mere results of a casual ignition or a secondary kind of action of the electricity, upon the particles which it finds in its course and thrusts aside in its passage (1454.).