1340. I formerly described a substance, sulphuret of silver, whose conducting power was increased by heat (433. 437. 438.); and I have since then met with another as strongly affected in the same way: this is fluoride of lead. When a piece of that substance, which had been fused and cooled, was introduced into the circuit of a voltaic battery, it stopped the current. Being heated, it acquired conducting powers before it was visibly red-hot in daylight; and even sparks could be taken against it whilst still solid. The current alone then raised its temperature (as in the case of sulphuret of silver) until it fused, after which it seemed to conduct as well as the metallic vessel containing it; for whether the wire used to complete the circuit touched the fused fluoride only, or was in contact with the platina on which it was supported, no sensible difference in the force of the current was observed. During all the time there was scarcely a trace of decomposing action of the fluoride, and what did occur, seemed referable to the air and moisture of the atmosphere, and not to electrolytic action.
1341. I have now very little doubt that periodide of mercury (414. 448. 691.) is a case of the same kind, and also corrosive sublimate (692.). I am also inclined to think, since making the above experiments, that the anomalous action of the protoxide of antimony, formerly observed and described (693. 801.), may be referred in part to the same cause.
1342. I have no intention at present of going into the particular relation of heat and electricity, but we may hope hereafter to discover by experiment the law which probably holds together all the above effects with those of the evolution and the disappearance of heat by the current, and the striking and beautiful results of thermo-electricity, in one common bond.
P viii. Electrolytic discharge.
1343. I have already expressed in a former paper (1164.), the view by which I hope to associate ordinary induction and electrolyzation. Under that view, the discharge of electric forces by electrolyzation is rather an effect superadded, in a certain class of bodies, to those already described as constituting induction and insulation, than one independent of and distinct from these phenomena.
1344. Electrolytes, as respects their insulating and conducting forces, belong to the general category of bodies (1320. 1334.); and if they are in the solid state (as nearly all can assume that state), they retain their place, presenting then no new phenomenon (426. &c.); or if one occur, being in so small a proportion as to be almost unimportant. When liquefied, they also belong to the same list whilst the electric intensity is below a certain degree; but at a given intensity (910. 912. 1007.), fixed for each, and very low in all known cases, they play a new part, causing discharge in proportion (783.) to the development of certain chemical effects of combination and decomposition; and at this point, move out from the general class of insulators and conductors, to form a distinct one by themselves. The former phenomena have been considered (1320. 1338.); it is the latter which have now to be revised, and used as a test of the proposed theory of induction.