Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.
acid of a known strength; the electric current was passed through a volta-electrometer (711.) having electrodes 4 inches long and 2.3 inches in width, so as to oppose as little obstruction as possible to the current; the gases evolved were collected and measured, and gave the quantity of water decomposed.  Then the whole of the charge used was mixed together, and a known part of it analyzed, by being precipitated and boiled with excess of carbonate of soda, and the precipitate well-washed, dried, ignited, and weighed.  In this way the quantity of metal oxidized and dissolved by the acid was ascertained; and the part removed from each zinc plate, or from all the plates, could be estimated and compared with the water decomposed in the volta-electrometer.  To bring these to one standard of comparison, I have reduced the results so as to express the loss at the plates in equivalents of zinc for the equivalent of water decomposed at the volta-electrometer:  I have taken the equivalent number of water as 9, and of zinc as 32.5, and have considered 100 cubic inches of the mixed oxygen and hydrogen, as they were collected over a pneumatic trough, to result from the decomposition of 12.68 grains of water.

1127.  The acids used in these experiments were three,—­sulphuric, nitric, and muriatic.  The sulphuric acid was strong oil of vitriol; one cubical inch of it was equivalent to 486 grains of marble.  The nitric acid was very nearly pure; one cubical inch dissolved 150 grains of marble.  The muriatic acid was also nearly pure, and one cubical inch dissolved 108 grains of marble.  These were always mixed with water by volumes, the standard of volume being a cubical inch.

1128.  An acid was prepared consisting of 200 parts water, 4-1/2 parts sulphuric acid, and 4 parts nitric acid; and with this both my trough containing forty pairs of three-inch plates, and four porcelain troughs, arranged in succession, each containing ten pairs of plates with double coppers four inches square, were charged.  These two batteries were then used in succession, and the action of each was allowed to continue for twenty or thirty minutes, until the charge was nearly exhausted, the connexion with the volta-electrometer being carefully preserved during the whole time, and the acid in the troughs occasionally mixed together.  In this way the former trough acted so well, that for each equivalent of water decomposed in the volta-electrometer only from 2 to 2.5 equivalents of zinc were dissolved from each plate.  In four experiments the average was 2.21 equivalents for each plate, or 88.4 for the whole battery.  In the experiments with the porcelain troughs, the equivalents of consumption at each plate were 3.51, or 141.6 for the whole battery.  In a perfect voltaic battery of forty pairs of plates (991. 1001.) the consumption would have been one equivalent for each zinc plate, or forty for the whole.

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Experimental Researches in Electricity, Volume 1 from Project Gutenberg. Public domain.