Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

1025.  In illustration of the effect of distance, an experiment like that described with two exciting pairs and one intervening plate (1012.), fig. 93, was arranged so that the distance between the plates in the third cell could be increased to six or eight inches, or diminished to the thickness of a piece of intervening bibulous paper.  Still the result was the same in both cases, the effect not being sensibly greater, when the plates were merely separated by the paper, than when a great way apart; so that the principal opposition to the current in this case does not depend upon the quantity of intervening electrolytic conductor, but on the relation of its elements to the intensity of the current, or to the chemical nature of the electrodes and the surrounding fluids.

1026.  When the acid was sulphuric acid, increasing its strength in any of the cells, caused no change in the effects; it did not produce a more intense current in the exciting cells (908.), or cause the current produced to traverse the decomposing cells more freely.  But if to very weak sulphuric acid a few drops of nitric acid were added, then either one or other of those effects could be produced; and, as might be expected in a case like this, where the exciting or conducting action bore a direct reference to the acid itself, increasing the strength of this (the nitric acid), also increased its powers.

1027.  The nature of the interposed plate was now varied to show its relation to the phenomena either of excitation or retardation, and amalgamated zinc was first substituted for platina.  On employing one voltaic pair and one interposed zinc plate, fig. 100, there was as powerful a current, apparently, as if the interposed zinc plate was away.  Hydrogen was evolved against P in cell ii, and against the side of the second zinc in cell i; but no gas appeared against the side of the zinc in cell ii, nor against the zinc in cell i.

1028.  On interposing two amalgamated zinc plates, fig. 101, instead of one, there was still a powerful current, but interference had taken place.  On using three intermediate zinc plates, fig. 102, there was still further retardation, though a good current of electricity passed.

1029.  Considering the retardation as due to the inaction of the amalgamated zinc upon the dilute acid, in consequence of the slight though general effect of diminished chemical power produced by the mercury on the surface, and viewing this inaction as the circumstance which rendered it necessary that each plate should have its tendency to decompose water assisted slightly by the electric current, it was expected that plates of the metal in the unamalgamated state would probably not require such assistance, and would offer no sensible impediment to the passing of the current.  This expectation was fully realized in the use of two and three interposed unamalgamated plates.  The electric current passed through them as freely as if there had been no such plates in the way.  They offered no obstacle, because they could decompose water without the current; and the latter had only to give direction to a part of the forces, which would have been active whether it had passed or not.

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Experimental Researches in Electricity, Volume 1 from Project Gutenberg. Public domain.