Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.
in the cell in, or against the two surfaces of that platina plate which separates the cells ii and iii, fig. 91, from each other.  It is evident that if that plate were away, the battery would consist of two pairs of plates and two cells, arranged in the most favourable position for the production of a current.  The platina plate therefore, which being introduced as at x, has oxygen evolved at one surface and hydrogen at the other (that is, if the decomposing current passes), may be considered as the cause of any obstruction arising from the decomposition of water by the electrolytic action of the current; and I have usually called it the interposed plate.

1010.  In order to simplify the conditions, dilute sulphuric acid was first used in all the cells, and platina for the interposed plates; for then the initial intensity of the current which tends to be formed is constant, being due to the power which zinc has of decomposing water; and the opposing force of decomposition is also constant, the elements of the water being unassisted in their separation at the interposed plates by any affinity or secondary action at the electrodes (744.), arising either from the nature of the plate itself or the surrounding fluid.

1011.  When only one voltaic pair of zinc and platina plates was used, the current of electricity was entirely stopped to all practical purposes by interposing one platina plate, fig. 92, i.e. by requiring of the current that it should decompose water, and evolve both its elements, before it should pass.  This consequence is in perfect accordance with the views before given (910. 917. 973.).  For as the whole result depends upon the opposition of forces at the places of electric excitement and electro-decomposition, and as water is the substance to be decomposed at both before the current can move, it is not to be expected that the zinc should have such powerful attraction for the oxygen, as not only to be able to take it from its associated hydrogen, but leave such a surplus of force as, passing to the second place of decomposition, should be there able to effect a second separation of the elements of water.  Such an effect would require that the force of attraction between zinc and oxygen should under the circumstances be at least twice as great as the force of attraction between the oxygen and hydrogen.

1012.  When two pairs of zinc and platina exciting plates were used, the current was also practically stopped by one interposed platina plate, fig. 93.  There was a very feeble effect of a current at first, but it ceased almost immediately.  It will be referred to, with many other similar effects, hereafter (1017.).

1013.  Three pairs of zinc and platina plates, fig. 94, were able to produce a current which could pass an interposed platina plate, and effect the electrolyzation of water in cell iv.  The current was evident, both by the continued deflection of the galvanometer, and the production of bubbles of oxygen and hydrogen at the electrodes in cell iv.  Hence the accumulated surplus force of three plates of zinc, which are active in decomposing water, is more than equal, when added together, to the force with which oxygen and hydrogen are combined in water, and is sufficient to cause the separation of these elements from each other.

Copyrights
Project Gutenberg
Experimental Researches in Electricity, Volume 1 from Project Gutenberg. Public domain.