Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

1004.  It might at first be imagined that amalgamated zinc would be much inferior in force to common zinc, because, of the lowering of its energy, which the mercury might be supposed to occasion over the whole of its surface; but this is not the case.  When the electric currents of two pairs of platina and zinc plates were opposed, the difference being that one of the zincs was amalgamated and the other not, the current from the amalgamated zinc was most powerful, although no gas was evolved against it, and much was evolved at the surface of the unamalgamated metal.  Again, as Davy has shown[A], if amalgamated and unamalgamated zinc be put in contact, and dipped into dilute sulphuric acid, or other exciting fluids, the former is positive to the latter, i.e. the current passes from the amalgamated zinc, through the fluid, to the unprepared zinc.  This he accounts for by supposing that “there is not any inherent and specific property in each metal which gives it the electrical character, but that it depends upon its peculiar state—­on that form of aggregation which fits it for chemical change.”

  [A] Philosophical Transactions, 1826, p. 405.

1005.  The superiority of the amalgamated zinc is not, however, due to any such cause, but is a very simple consequence of the state of the fluid in contact with it; for as the unprepared zinc acts directly and alone upon the fluid, whilst that which is amalgamated does not, the former (by the oxide it produces) quickly neutralizes the acid in contact with its surface, so that the progress of oxidation is retarded, whilst at the surface of the amalgamated zinc, any oxide formed is instantly removed by the free acid present, and the clean metallic surface is always ready to act with full energy upon the water.  Hence its superiority (1037.). 1006.  The progress of improvement in the voltaic battery and its applications, is evidently in the contrary direction at present to what it was a few years ago; for in place of increasing the number of plates, the strength of acid, and the extent altogether of the instrument, the change is rather towards its first state of simplicity, but with a far more intimate knowledge and application of the principles which govern its force and action.  Effects of decomposition can now be obtained with ten pairs of plates (417.), which required five hundred or a thousand pairs for their production in the first instance.  The capability of decomposing fused chlorides, iodides, and other compounds, according to the law before established (380. &c.), and the opportunity of collecting certain of the products, without any loss, by the use of apparatus of the nature of those already described (789. 814. &c.), render it probable that the voltaic battery may become a useful and even economical manufacturing instrument; for theory evidently indicates that an equivalent of a rare substance may be obtained at the expense of three or four equivalents of a very common body, namely, zinc:  and practice seems thus far to justify the expectation.  In this point of view I think it very likely that plates of platina or silver may be used instead of plates of copper with advantage, and that then the evil arising occasionally from solution of the copper, and its precipitation on the zinc, (by which the electromotive power of the zinc is so much injured,) will be avoided (1047.).

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Experimental Researches in Electricity, Volume 1 from Project Gutenberg. Public domain.