Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

982.  Fused nitre at a conducted much better than water:  I was unable to decide with certainty whether it was electrolyzed, but I incline to think not, for there was no discoloration against the platina at the cathode.  If sulpho-nitric acid had been used in the exciting vessel, both the nitre and the chloride of lead would have suffered decomposition like the water (906.).

983.  The results thus obtained of conduction without decomposition, and the necessity of a certain electrolytic intensity for the separation of the ions of different electrolytes, are immediately connected with the experiments and results given in S 10. of the Fourth Series of these Researches (418. 423. 444. 419.).  But it will require a more exact knowledge of the nature of intensity, both as regards the first origin of the electric current, and also the manner in which it may be reduced, or lowered by the intervention of longer or shorter portions of bad conductors, whether decomposable or not, before their relation can be minutely and fully understood.

984.  In the case of water, the experiments I have as yet made, appear to show, that, when the electric current is reduced in intensity below the point required for decomposition, then the degree of conduction is the same whether sulphuric acid, or any other of the many bodies which can affect its transferring power as an electrolyte, are present or not.  Or, in other words, that the necessary electrolytic intensity for water is the same whether it be pure, or rendered a better conductor by the addition of these substances; and that for currents of less intensity than this, the water, whether pure or acidulated, has equal conducting power.  An apparatus, fig. 84, was arranged with dilute sulphuric acid in the vessel A, and pure distilled water in the vessel B. By the decomposition at c, it appeared as if water was a better conductor than dilute sulphuric acid for a current of such low intensity as to cause no decomposition.  I am inclined, however, to attribute this apparent superiority of water to variations in that peculiar condition of the platina electrodes which is referred to further on in this Series (1040.), and which is assumed, as far as I can judge, to a greater degree in dilute sulphuric acid than in pure water.  The power therefore, of acids, alkalies, salts, and other bodies in solution, to increase conducting power, appears to hold good only in those cases where the electrolyte subject to the current suffers decomposition, and loses all influence when the current transmitted has too low an intensity to affect chemical change.  It is probable that the ordinary conducting power of an electrolyte in the solid state (419.) is the same as that which it possesses in the fluid state for currents, the tension of which is beneath the due electrolytic intensity.

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