Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

975.  Sulphate of soda in solution was then experimented with, for the purpose of ascertaining with respect to it, whether a certain electrolytic intensity was also required for its decomposition in this state, in analogy with the result established with regard to water (974).  The apparatus was arranged as in fig. 85; P and Z are the platina and zinc plates dipping into a solution of common salt; a and b are platina plates connected by wires of platina (except in the galvanometer g) with P and Z; c is a connecting wire of platina, the ends of which can be made to rest either on the plates a, b, or on the papers moistened in solutions which are placed upon them; so that the passage of the current without decomposition, or with one or two decompositions, was under ready command, as far as arrangement was concerned.  In order to change the anodes and cathodes at the places of decomposition, the form of apparatus fig. 86, was occasionally adopted.  Here only one platina plate, c, was used; both pieces of paper on which decomposition was to be effected were placed upon it, the wires from P and Z resting upon these pieces of paper, or upon the plate c, according as the current with or without decomposition of the solutions was required.

976.  On placing solution of iodide of potassium in paper at one of the decomposing localities, and solution of sulphate of soda at the other, so that the electric current should pass through both at once, the solution of iodide was slowly decomposed, yielding iodine at the anode and alkali at the cathode; but the solution of sulphate of soda exhibited no signs of decomposition, neither acid nor alkali being evolved from it.  On placing the wires so that the iodide alone was subject to the action of the current (900.), it was quickly and powerfully decomposed; but on arranging them so that the sulphate of soda alone was subject to action, it still refused to yield up its elements.  Finally, the apparatus was so arranged under a wet bell-glass, that it could be left for twelve hours, the current passing during the whole time through a solution of sulphate of soda, retained in its place by only two thicknesses of bibulous litmus and turmeric paper.  At the end of that time it was ascertained by the decomposition of iodide of potassium at the second place of action, that the current was passing and had passed for the twelve hours, and yet no trace of acid or alkali from the sulphate of soda appeared.

977.  From these experiments it may, I think, be concluded, that a solution of sulphate of soda can conduct a current of electricity, which is unable to decompose the neutral salt present; that this salt in the state of solution, like water, requires a certain electrolytic intensity for its decomposition; and that the necessary intensity is much higher for this substance than for the iodide of potassium in a similar state of solution.

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Experimental Researches in Electricity, Volume 1 from Project Gutenberg. Public domain.