Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

971.  It may be supposed, that the oxygen and hydrogen had been evolved in such small quantities as to have entirely dissolved in the water, and finally to have escaped at the surface, or to have reunited into water.  That the hydrogen can be so dissolved was shown in the first vessel; for after several days minute bubbles of gas gradually appeared upon a glass rod, inserted to retain the zinc and platina apart, and also upon the platina plate itself, and these were hydrogen.  They resulted principally in this way:—­notwithstanding the amalgamation of the zinc, the acid exerted a little direct action upon it, so that a small stream of hydrogen bubbles was continually rising from its surface; a little of this hydrogen gradually dissolved in the dilute acid, and was in part set free against the surfaces of the rod and the plate, according to the well-known action of such solid bodies in solutions of gases (623. &c.).

972.  But if the gases had been evolved in the second vessel by the decomposition of water, and had tended to dissolve, still there would have been every reason to expect that a few bubbles should have appeared on the electrodes, especially on the negative one, if it were only because of its action as a nucleus on the solution supposed to be formed; but none appeared even after twelve days.

973.  When a few drops only of nitric acid were added to the vessel A, fig. 84, then the results were altogether different.  In less than five minutes bubbles of gas appeared on the plates P’ and P” in the second vessel.  To prove that this was the effect of the electric current (which by trial at c was found at the same time to be passing,) the connexion at c was broken, the plates P’P” cleared from bubbles and left in the acid of the vessel B, for fifteen minutes:  during that time no bubbles appeared upon them; but on restoring the communication at c, a minute did not elapse before gas appeared in bubbles upon the plates.  The proof, therefore, is most full and complete, that the current excited by dilute sulphuric acid with a little nitric acid in vessel A, has intensity enough to overcome the chemical affinity exerted between the oxygen and hydrogen of the water in the vessel B, whilst that excited by dilute sulphuric acid alone has not sufficient intensity.

974.  On using a strong solution of caustic potassa in the vessel A, to excite the current, it was found by the decomposing effects at e, that the current passed.  But it had not intensity enough to decompose the water in the vessel B; for though left for fourteen days, during the whole of which time the current was found to be passing, still not the slightest appearance of gas appeared on the plates P’P”, nor any other signs of the water having suffered decomposition.

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Experimental Researches in Electricity, Volume 1 from Project Gutenberg. Public domain.