Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

890.  Then remove the acid from y, and introduce a drop of the solution of iodide of potassium at x (fig. 75.).  Exactly the same set of effects occur, except that when the metallic communication is made at PZ, the electric current is in the opposite direction to what it was before, as is indicated by the arrows, which show the courses of the currents (667.).

891.  Now both the solutions used are conductors, but the conduction in them is essentially connected with decomposition (858.) in a certain constant order, and therefore the appearance of the elements in certain places shows in what direction a current has passed when the solutions are thus employed.  Moreover, we find that when they are used at opposite ends of the plates, as in the last two experiments (889. 890.), metallic contact being allowed at the other extremities, the currents are in opposite directions.  We have evidently, therefore, the power of opposing the actions of the two fluids simultaneously to each other at the opposite ends of the plates, using each one as a conductor for the discharge of the current of electricity, which the other tends to generate; in fact, substituting them for metallic contact, and combining both experiments into one (fig. 76.).  Under these circumstances, there is an opposition of forces:  the fluid, which brings into play the stronger set of chemical affinities for the zinc, (being the dilute acid,) overcomes the force of the other, and determines the formation and direction of the electric current; not merely making that current pass through the weaker liquid, but actually reversing the tendency which the elements of the latter have in relation to the zinc and platina if not thus counteracted, and forcing them in the contrary direction to that they are inclined to follow, that its own current may have free course.  If the dominant action at y be removed by making metallic contact there, then the liquid at x resumes its power; or if the metals be not brought into contact at y but the affinities of the solution there weakened, whilst those active x are strengthened, then the latter gains the ascendency, and the decompositions are produced in a contrary order.

892.  Before drawing a final conclusion from this mutual dependence and state of the chemical affinities of two distant portions of acting fluids (916.), I will proceed to examine more minutely the various circumstances under which the re-action of the body suffering decomposition is rendered evident upon the action of the body, also undergoing decomposition, which produces the voltaic current.

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Experimental Researches in Electricity, Volume 1 from Project Gutenberg. Public domain.