[A] Philosophical Transactions, 1826, p. 406.
iii. Theory of Electro-chemical Decomposition.
477. The extreme beauty and value of electro-chemical decompositions have given to that power which the voltaic pile possesses of causing their occurrence an interest surpassing that of any other of its properties; for the power is not only intimately connected with the continuance, if not with the production, of the electrical phenomena, but it has furnished us with the most beautiful demonstrations of the nature of many compound bodies; has in the hands of Becquerel been employed in compounding substances; has given us several new combinations, and sustains us with the hope that when thoroughly understood it will produce many more.
478. What may be considered as the general facts of electrochemical decomposition are agreed to by nearly all who have written on the subject. They consist in the separation of the decomposable substance acted upon into its proximate or sometimes ultimate principles, whenever both poles of the pile are in contact with that substance in a proper condition; in the evolution of these principles at distant points, i.e. at the poles of the pile, where they are either finally set free or enter into union with the substance of the poles; and in the constant determination of the evolved elements or principles to particular poles according to certain well-ascertained laws.
479. But the views of men of science vary much as to the nature of the action by which these effects are produced; and as it is certain that we shall be better able to apply the power when we really understand the manner in which it operates, this difference of opinion is a strong inducement to further inquiry. I have been led to hope that the following investigations might be considered, not as an increase of that which is doubtful, but a real addition to this branch of knowledge.
480. It will be needful that I briefly state the views of electro-chemical decomposition already put forth, that their present contradictory and unsatisfactory state may be seen before I give that which seems to me more accurately to agree with facts; and I have ventured to discuss them freely, trusting that I should give no offence to their high-minded authors; for I felt convinced that if I were right, they would be pleased that their views should serve as stepping-stones for the advance of science; and that if I were wrong, they would excuse the zeal which misled me, since it was exerted for the service of that great cause whose prosperity and progress they have desired.