The Story of Alchemy and the Beginnings of Chemistry eBook

M. M. Pattison Muir
This eBook from the Gutenberg Project consists of approximately 171 pages of information about The Story of Alchemy and the Beginnings of Chemistry.

The Story of Alchemy and the Beginnings of Chemistry eBook

M. M. Pattison Muir
This eBook from the Gutenberg Project consists of approximately 171 pages of information about The Story of Alchemy and the Beginnings of Chemistry.
as playing a very important part in combustions; he said—­“Airs are divided into two categories; an air for the divine flame, which is the soul; and a material air which is the nourisher of sensible fire, and the basis of combustible matter.”  Sentences like that I have just quoted are found here and there in the writings of the earlier and later alchemists; now and again we also find statements which may be interpreted, in the light of the fuller knowledge we now have, as indicating at least suspicions that the atmosphere is a mixture of different kinds of air, and that only some of these take part in calcining and burning operations.  Those suspicions were confirmed by experiments on the calcination of metals and other substances, conducted in the 17th century by Jean Rey a French physician, and by John Mayow of Oxford.  But these observations and the conclusions founded on them, did not bear much fruit until the time of Lavoisier, that is, towards the close of the 18th century.  They were overshadowed and put aside by the work of Stahl (1660-1724).  Some of the alchemists of the 14th, 15th and 16th centuries taught that combustion and calcination are processes wherein the igneous principle is destroyed, using the word “destroyed” in its alchemical meaning.  This description of processes of burning was much more in keeping with the ideas of the time than that given by Boyle, Rey and Mayow.  It was adopted by Stahl, and made the basis of a general theory of those changes wherein one substance disappears and another, or others, very unlike it, are produced.

That he might bring into one point of view, and compare the various changes effected by the agency of fire, Stahl invented a new Principle, which he named Phlogiston, and constructed an hypothesis which is generally known as the phlogistic theory.  He explained, and applied, this hypothesis in various books, especially in one published at Halle in 1717.

Stahl observed that many substances which differed much from one another in various respects were alike in one respect; they were all combustible.  All the combustible substances, he argued, must contain a common principle; he named this supposed principle, phlogiston (from the Greek word phlogistos = burnt, or set on fire).  Stahl said that the phlogiston of a combustible thing escapes as the substance burns, and, becoming apparent to the senses, is named fire or flame.  The phlogiston in a combustible substance was supposed to be so intimately associated with something else that our senses cannot perceive it; nevertheless, the theory said, it is there; we can see only the escaping phlogiston, we can perceive only the phlogiston which is set free from its combination with other things.  The theory thought of phlogiston as imprisoned in the thing which can be burnt, and as itself forming part of the prison; that the prisoner should be set free, the walls of the prison had to be removed; the freeing of the prisoner destroyed the prison.  As escaping, or free, phlogiston was called fire, or flame, so the phlogiston in a combustible substance was sometimes called combined fire, or flame in the state of combination.  A peculiarity of the strange thing called phlogiston was that it preferred to be concealed in something, hidden, imprisoned, combined; free phlogiston* was supposed to be always ready to become combined phlogiston.

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The Story of Alchemy and the Beginnings of Chemistry from Project Gutenberg. Public domain.