Scientific American Supplement, No. 821, September 26, 1891 eBook

This eBook from the Gutenberg Project consists of approximately 151 pages of information about Scientific American Supplement, No. 821, September 26, 1891.

Scientific American Supplement, No. 821, September 26, 1891 eBook

This eBook from the Gutenberg Project consists of approximately 151 pages of information about Scientific American Supplement, No. 821, September 26, 1891.
---------------+--------------------+-----------------+
| Comparative Yield | Amount of | Substance. | of Furfuraldehyde. |Glucose Produced.| ---------------+--------------------+-----------------+ Cane sugar | 1.00 | .. | Starch | 0.50 | .. | Gum arabic | 1.33 | 34.72 | Gum arabic | 1.20 | 43.65 | Ghatti, 1 | 1.00 | 26.78 | Ghatti, 2 | 1.33 | 22.86 | Metarabin | 1.75 | .. | ---------------+--------------------+-----------------+ >

The amount of reducing sugar calculated as glucose is also appended.  This was estimated in the residue left in the flask after distillation by Fehling’s solution in the usual way.  The yields of furfuraldehyde would appear to have no definite relation to the other chemical data about a gum, such as the potash and baryta absorptions or the sugar produced on inversion.

The action of gum solutions upon polarized light is interesting, especially in view of the fact that arabin is itself strongly laevo-rotatory [alpha]_{D} = -99 deg., while certain gums are distinctly dextro-rotatory.  Hence it is evident that some other body besides arabin is present in the gum.  We have determined the rotatory power of a number of gum solutions, the results of which are subjoined.  On first commencing the experiments we experienced great difficulty from the nature of the solutions.  Most of them are distinctly yellow in color and almost opaque to light, even in dilute solutions such as 5 percent.  We found it necessary first to bleach the gums by a special process; 5 grammes of gum are dissolved in about 40 c.c. of lukewarm water, then a drop of potassium permanganate is added, and the solution is heated on a water bath with constant stirring until the permanganate is decomposed and the solution becomes brown.  A drop of sodium hydrogen sulphate is now added to destroy excess of permanganate.  At the same time the solution becomes perfectly colorless.

It can now be cooled down and made up to 100 c.c., yielding a 5 per cent. solution of which the rotatory power can be taken with ease.  Using a 20 mm. tube and white light the above numbers were obtained.

----------------+----------------+-----------------
Gum or Dextrin. | Solution used. |    [alpha]_{D}
----------------+----------------+-----------------
|   Per Cent.    |
Aden, 1         |       5        |     — 33.8
Cape, 2         |       5        |     + 28.6
Indian, 3       |       5        |     + 66.2
Eastern, 4      |       5        |     — 26.0
Eastern, 5      |       5        |     — 30.6
Senegal, 6      |       5        |     — 17.6
Senegal, 7      |       5        |     — 18.4
Senegal, 8      |       21/2       |     — 19.6
Senegal, 9      |       5        |     — 38.2
Senegal, 10     |       5        |     — 25.8

Copyrights
Project Gutenberg
Scientific American Supplement, No. 821, September 26, 1891 from Project Gutenberg. Public domain.